MEDIUM EFFECTS IN UNSYMMETRICAL DISULFIDES COMPOUNDS SYNTHESIS FROM BUNTE SALTS

被引:28
|
作者
HIVER, P
DICKO, A
PAQUER, D
机构
[1] Laboratoire de Chimie Organique, Université de Metz, 57045 Metz, Ile du Saulcy
关键词
D O I
10.1016/0040-4039(94)88513-3
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The present study allows us to show the influence of the polarity of the reaction, medium as well as the electron-donating and withdrawing character of para substituents of alpha-halogeno tuluenes in the preparation of unsymmetrical disulfides using the Bunte salt method. The use of DMSO as a reaction solvent permits not only to dissociate the sodium salt, but also to synthesise unsymmetrical disulfides from compounds, which are inadequate using conventional methods.
引用
收藏
页码:9569 / 9572
页数:4
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