Crystal structure of high-spin tetraaquabis(2-chloropyrazine-kappa N-4)iron(II) bis(4-methylbenzene-sulfonate)

被引：0
|
作者：
Golub, Bohdan O. [1 ]
Shylin, Sergii I. [1 ]
Dechert, Sebastian [2 ]
Malysheva, Maria L. [1 ]
Gural'skiy, Il'ya A. [1 ]
机构：
[1] Taras Shevchenko Natl Univ Kyiv, Dept Chem, Volodymyrska St 64-13, UA-01601 Kiev, Ukraine
[2] Univ Gottingen, Inst Inorgan Chem, D-37077 Gottingen, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; iron(II) complex; 2-chloropyrazine; hydrogen bonding; pi-pi contacts;
D O I：
10.1107/S2056989015010713
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title salt, [Fe II (C4H3ClN2)(2)(H2O)(4)](C7H7O3S)(2), contains a complex cation with point group symmetry 2/m. The high-spin Fe-II cation is hexacoordinated by four symmetry-related water and two N-bound 2-chloropyrazine molecules in a trans arrangement, forming a distorted FeN2O4 octahedron. The three-dimensional supramolecular structure is supported by intermolecular O-H center dot center dot center dot O hydrogen bonds between the complex cations and tosylate anions, and additional pi-pi interactions between benzene and pyrazine rings. The methyl H atoms of the tosylate anion are equally disordered over two positions.
引用
收藏
页码：776 / +
页数：7
相关论文
共 50 条
  • [1] Crystal structure of bis(piperazin-1-ium-kappa N-4) bis(thiosulfato-kappa S)zinc(II) dihydrate
    Paul, Avijit Kumar
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 176 - +
  • [2] Crystal structure of bis[(phenylmethanamine-kappa N)(phthalocyaninato-kappa N-4) zinc] phenylmethanamine trisolvate
    Shamsudin, Norzianah
    Tan, Ai Ling
    Wimmer, Franz L.
    Young, David J.
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 1026 - +
  • [3] Crystal structure of triaqua(2,6-dimethylpyrazine-kappa N-4)bis(thiocyanato-kappa N)manganese(II) 2,5-dimethylpyrazine disolvate
    Suckert, Stefan
    Woehlert, Susanne
    Jess, Inke
    Naether, Christian
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M223 - U194
  • [4] Crystal structure of bis(benzylamine-kappa N)[5,10,15,20-tetrakis(4-chlorophenyl)porphyrinato-kappa N-4]iron(II) n-hexane monosolvate
    Dhifaoui, Selma
    Harhouri, Wafa
    Bujacz, Anna
    Nasri, Habib
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 102 - +
  • [5] Crystal structure of tetraaquabis(thiocyanato-kappa N)nickel(II)-2,5-dimethylpyrazine (1/4)
    Suckert, Stefan
    Wriedt, Mario
    Jess, Inke
    Naether, Christian
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M18 - U67
  • [6] Crystal structure of diaquabis(2,6-dimethylpyrazine-kappa N-4)bis(thiocyanato-kappa N)cobalt(II) 2,5-dimethylpyrazine monosolvate
    Suckert, Stefan
    Woehlert, Susanne
    Jess, Hike
    Naether, Christian
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M242 - U301
  • [7] Crystal structure of tetrakis( mu-N-phenylacetamidato)-kappa N-4:O;kappa O-4:N-bis[(2methylbenzonitrile-kappa N) rhodium( II)]( Rh-Rh)
    Eagle, Cassandra T.
    Atem-Tambe, Nkongho
    Kpogo, Kenneth K.
    Tan, Jennie
    Cook, Kevin M.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M333 - +
  • [8] Crystal structure of bis(4-acetylpyridine-kappa N)bis(ethanol-kappa O)bis(thiocyanato-kappa N)-manganese(II)
    Werner, Julia
    Jess, Inke
    Naether, Christian
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M81 - U77
  • [9] Crystal structure of bis[trans-(1,4,8,11-tetraazacyclotetradecane-kappa N-4)bis(thiocyanato-kappa N)chromium( III)] tetrachloridozincate from synchrotron data
    Moon, Dohyun
    Ryoo, Keon Sang
    Choi, Jong-Ha
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 540 - +
  • [10] Crystal structure of tris(1,10-phenanthroline-kappa(2) N, N ') iron(II) bis[bis(trifluoromethylsulfonyl)imide] monohydrate
    Teramoto, Kazunori
    Kawasaki, Takeshi
    Nishide, Toshikazu
    Ikeda, Yasuhisa
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M8 - +
12345