CONSTITUENTS OF TROPICAL MEDICINAL-PLANTS .62. APORPHINOID ALKALOIDS AND TERPENOIDS FROM PIPTOSTIGMA-FUGAX

被引：40
作者：
ACHENBACH, H
SCHWINN, A
机构：
[1] Institute of Pharmacy and Food Chemistry, Department of Pharmaceutical Chemistry, University of Erlangen
来源：
PHYTOCHEMISTRY | 1995年 / 38卷 / 04期
关键词：
PIPTOSTIGMA FUGAX; ANNONACEAE; ROOTS; STEM BARK; APORPHINOIDS; 5-ALPHA-CYCLOART-24-ENE-3-BETA; 16-BETA; 21-TRIOL; 4-HYDROXY-4,7-DIMETHYL-1-TETRALONE; N-METHYLHETEROPSINE; ONYCHINES;
D O I：
10.1016/0031-9422(94)00675-J
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Thirty-eight compounds were isolated from the roots and stem bark of Piptostigma fugax, besides three fractions of mixtures of homologues of two 6'-acylated sterol glucosides and fatty acids, respectively. Structures were determined by spectroscopic and chemical methods. Mixtures of homologues were analysed by GC-mass spectrometry after derivatization. 5 alpha-Cycloart-24-ene-3 beta,16 beta,21-triol, 4-hydroxy-4,7-dimethyl-1-tetralone and three onychine-type alkaloids (2,7-dihydroxyonychine, 7-hydroxy-2-methoxyonychine and 7-hydroxy-2,8-dimethoxyonychine) represent new compounds. N-Methylheteropsine has been isolated as a natural product for the first time.
引用
收藏
页码：1037 / 1048
页数：12
相关论文
共 50 条
[1]   CONSTITUENTS OF TROPICAL MEDICINAL-PLANTS .63. SYNTHESIS OF 2-METHOXYONYCHINE ALKALOIDS - STRUCTURE REVISION OF OXYLOPIDINE [J].
ACHENBACH, H ;
SCHWINN, A .
ARCHIV DER PHARMAZIE, 1994, 327 (12) :755-762
[2]  
ACHENBACH H, 1982, LIEBIGS ANN CHEM, P1623
[3]   CARDIOACTIVE STEROID SAPONINS AND OTHER CONSTITUENTS FROM THE AERIAL PARTS OF TRIBULUS CISTOIDES [J].
ACHENBACH, H ;
HUBNER, H ;
BRANDT, WG ;
REITER, M .
PHYTOCHEMISTRY, 1994, 35 (06) :1527-1543
[4]   CONSTITUENTS OF TROPICAL MEDICINAL-PLANTS .54. CYCLOARTANES AND OTHER TERPENOIDS AND PHENYLPROPANOIDS FROM MONOCYCLANTHUS-VIGNEI [J].
ACHENBACH, H ;
FREY, D .
PHYTOCHEMISTRY, 1992, 31 (12) :4263-4274
[5]   ALKALOIDS OF THE ANNONACAEE .74. 3 BIS-DEHYDROAPORPHINES FROM OXANDRA CF MAJOR [J].
ARANGO, G ;
CORTES, D ;
CAVE, A .
PHYTOCHEMISTRY, 1987, 26 (04) :1227-1229
[6]   SYNTHESIS OF OPTICALLY ACTIVE METHYLTETRALINES AND METHYL-1-TETRALONES - STUDY ON THEIR CONFORMATIONS USING CIRCULAR DICHROISM [J].
BARRY, J ;
KAGAN, HB ;
SNATZKE, G .
TETRAHEDRON, 1971, 27 (19) :4737-&
[7]   H-1 AND C-13 ASSIGNMENTS FROM SENSITIVITY-ENHANCED DETECTION OF HETERONUCLEAR MULTIPLE-BOND CONNECTIVITY BY 2D MULTIPLE QUANTUM NMR [J].
BAX, A ;
SUMMERS, MF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (08) :2093-2094
[8]   SENSITIVITY-ENHANCED TWO-DIMENSIONAL HETERONUCLEAR SHIFT CORRELATION NMR-SPECTROSCOPY [J].
BAX, A ;
SUBRAMANIAN, S .
JOURNAL OF MAGNETIC RESONANCE, 1986, 67 (03) :565-569
[9]  
BISHARA RH, 1970, LLOYD, V33, P477
[10]   SYNTHESIS OF CYCLOARTENOL VIA 19-OXYGENATED LANOSTANES [J].
BOAR, RB ;
COPSEY, DB .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1979, (02) :563-564
12345