KINETICS AND MECHANISM OF GENERAL-ACID-ASSISTED OXIDATION OF BROMIDE BY HYPOCHLORITE AND HYPOCHLOROUS ACID

被引：303

作者：

KUMAR, K ^{[1
]}

MARGERUM, DW ^{[1
]}

机构：

[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

来源：

INORGANIC CHEMISTRY | 1987年 / 26卷 / 16期

关键词：

D O I：

10.1021/ic00263a030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：2706 / 2711

页数：6

共 16 条

[1] HALOGEN CATIONS [J].

AROTSKY, J ;

SYMONS, MCR .

QUARTERLY REVIEWS, 1962, 16 (03) :282-297

[2] THE ABSORPTION SPECTRA OF I-2,I-3-,I-, IO3-,S4O6 AND S2O3= HEAT OF THE REACTION I-3-=I-2+I- [J].

AWTREY, AD ;

CONNICK, RE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (04) :1842-1843

[3] STABILITY CONSTANTS AND ABSORPTION SPECTRA OF IONS BR2CL- AND BRCL2- [J].

BELL, RP ;

PRING, M .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1966, (11) :1607-&

[4]

BELL RP, 1973, PROTON CHEM, P198

[5] EXTENSION OF ACCESSIBLE FIRST-ORDER RATE CONSTANTS AND ACCURATE DEAD-TIME DETERMINATIONS FOR STOPPED-FLOW SPECTROSCOPY [J].

DICKSON, PN ;

MARGERUM, DW .

ANALYTICAL CHEMISTRY, 1986, 58 (14) :3153-3158

[6]

EDWARDS JO, 1964, INORGANIC REACTION M, P74

[7] KINETICS OF HALOGEN HYDROLYSIS [J].

EIGEN, M ;

KUSTIN, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (08) :1355-&

[8] THE REACTION BETWEEN HYPOCHLORITE AND BROMIDES [J].

FARKAS, L ;

LEWIN, M ;

BLOCH, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (06) :1988-1991

[9]

KOLTHOFF IM, 1969, QUANTITATIVE CHEM AN, P796

[10] ATOM-TRANSFER REDOX KINETICS - GENERAL-ACID-ASSISTED OXIDATION OF IODIDE BY CHLORAMINES AND HYPOCHLORITE [J].

KUMAR, K ;

DAY, RA ;

MARGERUM, DW .

INORGANIC CHEMISTRY, 1986, 25 (24) :4344-4350

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