USE OF REDOX REACTIONS IN ANALYSIS OF DYES AND DYE INDUSTRY INTERMEDIATES .4. OXIDATION OF BENZIDINE, ORTHO-TOLIDINE, AND ORTHO-DIANISIDINE WITH CHLORAMINE-T AND N-BROMOSUCCINIMIDE

被引：7
作者：
BAREK, J
BERKA, A
JAKUBEC, K
机构：
[1] Department of Analytical Chemistry, Charles University
来源：
MICROCHEMICAL JOURNAL | 1978年 / 23卷 / 03期
关键词：
D O I：
10.1016/0026-265X(78)90087-5
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The oxidation of benzidine, o-tolidine, and o-dianisidine with chloramine T and N-bromosuccinimide was studied, the stoichiometry was established, and a mechanism was proposed. An extraction-photometric determination of these diamines was developed, based on the reaction with excess chloramine T or N-bromosuccinimide and the measurement of the absorbance of the N,N′-dihalogeno-diphenoquinonediimines formed, after their extraction into chloroform. © 1978.
引用
收藏
页码：341 / 352
页数：12
相关论文
共 8 条
[1]   OXIDATION OF ORGANIC-SUBSTANCES WITH TRIVALENT MANGANESE COMPOUNDS .6. OXIDATION OF BENZIDINE, ORTHO-TOLIDINE AND ORTHO-DIANISIDINE WITH DIPHOSPHATE COMPLEX OF TRIVALENT MANGANESE IN BUFFER SOLUTION [J].
BAREK, J ;
BERKA, A .
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1977, 42 (06) :1949-1959
[2]   OXIDATION OF ORGANIC-SUBSTANCES WITH TRIVALENT MANGANESE COMPOUNDS .5. OXIDATION OF BENZIDINE, ORTHO,ORTHO'-TOLIDINE AND ORTHO,ORTHO'-DIANISIDINE USING DIPHOSPHATE COMPLEX OF TRIVALENT MANGANESE AND MANGANESE(III) SULFATE [J].
BAREK, J ;
BERKA, A .
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1976, 41 (05) :1334-1342
[3]   UBER DIE OXYDIERENDE WIRKUNG DES N-BROMSUCCINIMIDS [J].
BERKA, A ;
ZYKA, J .
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1958, 23 (03) :402-407
[4]  
BERKA A, 1965, NEWER REDOX TITRANTS, P185
[5]  
JAKUBEC K, 1977, THESIS CHARLES U
[6]  
MATRKA M, 1971, CHEM PRUM, V21, P14
[7]  
MATRKA M, 1970, COLL CZECHOSLOV CHEM, V35, P701
[8]  
MCMILLAN A, 1927, J CHEM SOC IND, V46, pT472
1