SUNLIGHT-INITIATED CYCLOADDITION REACTIONS OF THE BENZENE-RING

被引：0
作者：
ALQARADAWI, SY
BLAKEMORE, DC
GILBERT, A
机构：
[1] UNIV READING,DEPT CHEM,POB 224,READING RG6 2AD,BERKS,ENGLAND
[2] QATAR UNIV,DEPT CHEM,DOHA,QATAR
来源：
PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES | 1993年 / 105卷 / 06期
关键词：
SUNLIGHT; PHOTOCYCLOADDITION; BENZOCYCLOBUTENE; TRIQUINANE;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Both 1,2-(ortho) and 1,3-(meta) cycloaddition of ethenes to the benzene ring can be accomplished using sunlight-initiated chemistry. The process is most effective for arenes which have both electron-donor and electron-acceptor substituents and occurs both inter- and intramolecularly giving an inexpensive and convenient access to complex molecular skeletons from readily available starting materials.
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页码：555 / 562
页数：8
相关论文
共 39 条
[1]  
ALJALAL N, 1983, J CHEM RES-S, P266
[2]   PHOTOCYCLOADDITION OF ETHENES TO CYANOANISOLES [J].
ALJALAL, N ;
GILBERT, A ;
HEATH, P .
TETRAHEDRON, 1988, 44 (05) :1449-1459
[3]   THE SYNTHESIS OF AZOCINE DERIVATIVES BY THE PHOTOCYCLOADDITION OF PHENOLS TO 1-NAPHTHONITRILE AND 4-METHOXY-1-NAPHTHONITRILE [J].
ALJALAL, NA .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1990, 54 (01) :99-104
[4]   INTRAMOLECULAR PHOTOCYCLOADDITION OF 4-PHENOXYBUT-1-ENES - A CONVENIENT ACCESS TO THE 4-OXATRICYCLO[7.2.0.0(3,7)]UNDECA-2,10-DIENE SKELETON [J].
ALQARADAWI, SY ;
COSSTICK, KB ;
GILBERT, A .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1992, (09) :1145-1148
[5]  
ANDREWS LJ, 1964, MOL COMPLEXES ORGANI
[6]  
ANGUS HJF, 1959, P CHEM SOC LONDON, P326
[7]   THE 1ST GENERAL INDEX OF MOLECULAR COMPLEXITY [J].
BERTZ, SH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (12) :3599-3601
[8]  
BREUER A, 1878, BERICHTE, V11, P1403
[9]  
BRYCESMITH D, 1962, CHEM IND-LONDON, P2060
[10]   ORGANIC-PHOTOCHEMISTRY OF BENZENE .2. [J].
BRYCESMITH, D ;
GILBERT, A .
TETRAHEDRON, 1977, 33 (19) :2459-2490
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