(Acetylacetonato-kappa O-2,O ') dichloridobis(methanolato-kappa O) niobium(V)

被引：5
作者：
Herbst, Leandra [1 ]
Visser, Hendrik G. [1 ]
Roodt, Andreas [1 ]
Pretorius, Carla [1 ]
机构：
[1] Univ Free State, Dept Chem, POB 339, ZA-9300 Bloemfontein, South Africa
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
data-to-parameter ratio = 22.9; mean ̄(C-C) = 0.003 Å; R factor = 0.026; single-crystal X-ray study; T = 100 K; wR factor = 0.060;
D O I：
10.1107/S1600536812042638
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Nb(CH3O)(2)(C5H7O2)Cl-2], a slightly distorted octahedral coordination geometry is observed around the Nb V atom with Nb-O distances in the range of 1.8254 ( 16)-2.0892 ( 16) angstrom and Nb-Cl distances of 2.3997 (14) and 2.4023 (12) angstrom. The O-Nb-O angles vary between 81.36 (7) and 172.65 (7)degrees, while the trans Cl-Nb-Cl angle is 167.34 (2)degrees. There are no hydrogen bonds observed.
引用
收藏
页码：M1392 / +
页数：6
相关论文
共 50 条
  • [41] Diaquabis[N-(2-fluorobenzyI)-N-nitroso-hydroxylaminato-kappa O-2,O ']nickel(II)
    Kovalchukova, Olga
    Bostanabad, Ali Sheikh
    Stash, Adam
    Strashnova, Svetlana
    Zyuzin, Igor
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M98 - +
  • [42] Bis[4,4,5,5-tetramethyl-2-(pyridin-2-yl-kappa N-2) imidazoline-1-oxyl 3-oxide-kappa O] tris(nitrato-kappa O-2,O ') terbium(III)
    Li, Dong-jiao
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1341 - +
  • [43] (Dimethyl sulfoxide-kappa O)[2-({(ethylsul-fanyl)[2-(2-oxidobenzylidene-kappa O) hydrazinylidene-kappa N-2]methyl}iminomethyl)-phenolato-kappa O] dioxidouranium(VI)
    Takjoo, Reza
    Ng, Seik Weng
    Tiekink, Edward R. T. }
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M244 - U377
  • [44] catena-Poly[[aquabis(4-formylbenzoato-kappa O-2(1),O-1 ')cadmium]-mu-pyrazine-kappa N-2:N']
    Celik, Fatih
    Dilek, Nefise
    Delibas, Nagihan Caylak
    Necefoglu, Hacali
    Hokelek, Tuncer
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M37 - +
  • [45] Poly[aqua(mu(2)-pyrimidine-2-carboxylato-kappa O-4,N:O ',N ')(nitrato-kappa O)cadmium]
    In-noi, Orrasa
    Chainok, Kittipnog
    Harding, David J.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1349 - +
  • [46] {4-Bromo-2-[(2-{(ethylsulfanyl)[(2-oxidobenzylidene-kappa O)amino-kappa N] methylidene}hydrazinylidene-kappa N-1)methyl]phenolato-kappa O}(butan-2-ol-kappa O) dioxidouranium(VI)
    Takjoo, Reza
    Ahmadi, Mehdi
    Ng, Seik Weng
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M279 - U598
  • [47] Poly[diaquabis(mu-4,4'-bipyridine-kappa N-2: N') bis(ethane- 1,2- diol-kappa O) bis(mu- sulfato-kappa O-2:O')dicobalt(II)]
    Zhong, Kai-Long
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M207 - +
  • [48] Bis(1,10-phenanthroline-kappa N-2,N ')(sulfato-kappa O-2,O ')nickel(II) butane-2,3-diol monosolvate
    Zhong, Kai-Long
    Ni, Chao
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1519 - +
  • [49] Poly[[tris(mu(2)-acetato-kappa O-2:O')(4-chlorobenzene-1,2-diamine-kappa N)(mu(3)-hydroxido)-dizinc] ethanol monosolvate]
    Geiger, David K.
    Parsons, Dylan E.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M247 - +
  • [50] (1H-Pyrazole-kappa N)bis(tri-tert-butoxy-silanethiolato-kappa O-2,S)cadmium
    Baranowska, Katarzyna
    Bulman, Mateusz
    Dolega, Anna
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1515 - +
12345