ANALYSIS OF FE, CU, NI AND CO IN FLUORIDE GLASSES AND THEIR PRECURSORS

被引：8

作者：

NEWMAN, PJ ^{[1
]}

VOELKEL, AT ^{[1
]}

MACFARLANE, DR ^{[1
]}

机构：

[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 1995年 / 184卷

关键词：

D O I：

10.1016/0022-3093(94)00636-9

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A method for the determination of iron, copper, nickel and cobalt in zirconium fluoride and heavy metal fluoride glasses is presented. This method involves dissolution in a boric acid solution, complexation of transition metal ions with sodium diethyl dithiocarbamate and ammonium pyrrolidine dithiocarbamate at pH 2.2, extraction of the complexes with methyl isobutyl ketone, back extraction with Hg (II) solution and graphite furnace atomic absorption spectroscopy analysis. This method is applicable for determination of Fe, Cu, Ni and Co at concentrations < 1 ppm.

引用

页码：324 / 328

页数：5

共 15 条

[1] ELECTROCHEMICAL PURIFICATION AND GFAAS ANALYSIS OF HEAVY-METAL FLUORIDE GLASS [J].