REACTIONS OF 1,1-DIPHENYL-2-METHYLPROPENE CATION RADICALS WITH METHANOL - KETONE FORMATION INVOLVING CARBOCATION REARRANGEMENT

被引：5

作者：

AKABA, R ^{[1
]}

AIHARA, S ^{[1
]}

SAKURAGI, H ^{[1
]}

TOKUMARU, K ^{[1
]}

机构：

[1] UNIV TSUKUBA, DEPT CHEM, TSUKUBA, IBARAKI 305, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 04期

关键词：

D O I：

10.1246/bcsj.64.1419

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Anodic oxidation of 1,1-diphenyl-2-methyl-propene (1) in an acetonitrile-methanol mixture under argon gave 3,3-diphenyl-2-butanone (2) in high yield together with small amounts of 1,2-diphenyl-2-methyl-1-propanone (3) and benzophenone (4). Similar anodic oxidation of 1 in the presence of oxygen was also carried out, and the mechanisms for the novel ketone forming reactions are discussed.

引用

页码：1419 / 1421

页数：3

共 28 条

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