APPLICATION OF SCALED PARTICLE THEORY TO ALKYL-ARYL SURFACTANTS - A 2 ZONE MODEL OF MICELLAR CORE

被引：3
|
作者：
NANDI, N
机构：
[1] Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore
来源：
JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM | 1995年 / 332卷 / 03期
关键词：
D O I：
10.1016/0166-1280(94)03897-T
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Scaled Particle Theory (SPT) has been applied to predict the total free energies of micellization of ionic as well as nonionic micellar systems containing an aryl ring. A modification of the previously developed model has been made, proposing a two-zone model of micellar core which corroborates with the structural information available for such systems. The results are in good agreement with experimental data and also confirm the dictating role of cavity forming free energies for such systems.
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页码：301 / 311
页数：11
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