INTERACTION BETWEEN TRINUCLEAR OXO-CENTERED COORDINATION-COMPOUNDS OF TRANSITION-METALS AND ORGANIC-SOLVENTS

被引：3

作者：

WARNKE, Z

WAWRZYNIAK, G

CHMURZYNSKI, L

机构：

[1] Department of Chemistry, University of Gdańsk

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1993年 / 28卷 / 3-4期

关键词：

COMPLEXES; IRON(III); CHROMIUM(III); DIMETHYLSULFOXIDE; METHANOL; CONDUCTOMETRY; SOLVATION;

D O I：

10.1080/00958979308037108

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A number of oxo-centred trinuclear complexes have been obtained, of general formula [M3O(OOCR)6L3]X (R=H, CH3; M=Cr(III), Fe(III); L=pyridine, 4-picoline; X=NO3-, ClO4-). The behaviour of these compounds in absolute methanol and in dimethylsulphoxide was investigated by the conductometric method. Dissociation constants of the complexes were determined. Molar conductivities and solvodynamic radii of the cations were also evaluated. It has been shown that the cations do not undergo solvation to any measurable extent.

引用

页码：271 / 278

页数：8

共 39 条

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[24] COORDINATION-COMPOUNDS OF HYDRAZINE DERIVATIVES WITH TRANSITION-METALS .23. COBALT(II) CHELATES OF BIS(N-SALICYLIDENE)DICARBOXYLIC ACID DIHYDRAZIDES
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[27] COORDINATION-COMPOUNDS OF HYDRAZINE DERIVATIVES WITH TRANSITION-METALS .24. COORDINATION CHEMISTRY OF HYDRAZINE-S-METHYL CARBODITHIOATE SCHIFF-BASES DERIVED FROM BETA-DICARBONYL COMPOUNDS
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TRANSITION METAL CHEMISTRY, 1982, 7 (03) : 135 - 140
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[29] COORDINATION-COMPOUNDS OF HYDRAZINE DERIVATIVES WITH TRANSITION-METALS .12. NICKEL(II) AND COPPER(II) CHELATES OF BIS(N-SALICYLIDENE)DICARBOXYLIC ACID DIHYDRAZIDES
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[30] COORDINATION-COMPOUNDS OF HYDRAZINE DERIVATIVES WITH TRANSITION-METALS .7. METAL(II) COMPLEXES WITH HYDRAZINE S-METHYL DITHIOCARBOXYLATE SCHIFF-BASES AND THEIR PYRIDINE ADDUCTS
ELSAYED, L
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JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1974, 36 (08): : 1739 - 1743

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