Crystal structure of [butane-2,3-dione bis(4-methylthiosemicarbazonato)-kappa S-4,N-1,N-1',S]- (pyridine-kappa N)zinc(II)

被引：2

作者：

Brown, Oliver C. ^{[1
]}

Tocher, Derek A. ^{[2
]}

Blower, Philip J. ^{[3
]}

Went, Michael J. ^{[1
]}

机构：

[1] Univ Kent, Sch Phys Sci, Canterbury CT2 7NH, Kent, England

[2] UCL, Dept Chem, London WC1H 0AJ, England

[3] Kings Coll London, Div Imaging Sci & Biomed Engn, St Thomas Hosp, London SE1 7EH, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷

关键词：

crystal structure; bis(thiosemicarbazone); copper; zinc; hypoxia; PET;

D O I：

10.1107/S2056989015019234

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the structure of the title complex, [Zn(C8H14N6S2)(C5H5N)], the Zn-II ion has a pseudo-square-pyramidal coordination environment and is displaced by 0.490 A from the plane of best fit defined by the bis(thiosemicarbazonate) N2S2 donor atoms. Chains sustained by intermolecular " N-H center dot center dot center dot N and N-H center dot center dot center dot S hydrogen-bonding interactions extend parallel to [10 (1) over bar].

引用

页码：1349 / +

页数：8

共 10 条

[1]

[Anonymous], 2014, CRYSALIS PRO

[2] Surface functional polymer library by post-polymerisation modification using diarylmethylenes: metal ligand catch and release [J].

Aphaiwong, Apichat ;

Moloney, Mark G. ;

Christlieb, Martin .

JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (47) :24627-24636

[3] Controlled Axial Coordination: Solid-Phase Synthesis and Purification of Metallo-Radiopharmaceuticals [J].

Betts, Helen M. ;

Barnard, Peter J. ;

Bayly, Simon R. ;

Dilworth, Jonathan R. ;

Gee, Antony D. ;

Holland, Jason P. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (44) :8416-8419

[4] Structural trends in copper(II) bis(thiosemicarbazone) radiopharmaceuticals [J].

Blower, PJ ;

Castle, TC ;

Cowley, AR ;

Dilworth, JR ;

Donnelly, PS ;

Labisbal, E ;

Sowrey, FE ;

Teat, SJ ;

Went, MJ .

DALTON TRANSACTIONS, 2003, (23) :4416-4425

[5]

Brown O. C., 2015, THESIS

[6] Copper bis(thiosemicarbazone) complexes as hypoxia imaging agents: structure-activity relationships [J].

Dearling, JLJ ;

Lewis, JS ;

Muller, GED ;

Welch, MJ ;

Blower, PJ .

JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 2002, 7 (03) :249-259

[7] OLEX2: a complete structure solution, refinement and analysis program [J].

Dolomanov, Oleg V. ;

Bourhis, Luc J. ;

Gildea, Richard J. ;

Howard, Judith A. K. ;

Puschmann, Horst .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 :339-341

[8] Functionalized bis(thiosemicarbazonato) complexes of zinc and copper: Synthetic platforms toward site-specific radiopharmaceuticals [J].

Holland, Jason P. ;

Aigbirhio, Franklin I. ;

Betts, Helen M. ;

Bonnitcha, Paul D. ;

Burke, Paul ;

Christlieb, Martin ;

Churchill, Grant C. ;

Cowley, Andrew R. ;

Dilworth, Jonathan R. ;

Donnelly, Paul S. ;

Green, Jennifer C. ;

Peach, Josephine M. ;

Vasudevan, Sridhar R. ;

Warren, John E. .

INORGANIC CHEMISTRY, 2007, 46 (02) :465-485

[9] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[10]

Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053229614024218, 10.1107/S0108767307043930]

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