PREPARATION AND PROPERTIES OF A 1-1 COMPLEX OF TETRATHIAFULVALENE AND 1,3,5-TRINITROBENZENE (TTF-TNB)

被引：8

作者：

BRYCE, MR

DAVIES, SR

机构：

[1] Univ of Durham, Durham, Engl, Univ of Durham, Durham, Engl

来源：

SYNTHETIC METALS | 1987年 / 20卷 / 03期

关键词：

SEMICONDUCTING ORGANIC COMPOUNDS;

D O I：

10.1016/0379-6779(87)90834-4

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A neutral, crystalline 1:1 complex of tetrathiafulvalene and 1,3,5-trinitrobenzene has been prepared and characterized by a range of solidstate techniques. All data suggest that TTF-TNB is essentially a neutral complex. The magnetic susceptibility of the complex between 22 K and 296 K is constant. The lack of charge transfer is evident from the very low intensity of the peak assigned to the TTF radical cation in the solid-state u. v. -visible spectrum (2. 8 eV) and from the extremely weak solid-state e. s. r. signal obtained from the complex.

引用

页码：373 / 374

页数：2

共 9 条

[1] ELECTROCONDUCTIVE CHARGE-TRANSFER COMPLEXES OF 2,4,6-TRICYANO-S-TRIAZINE AND OF 3,6-DICYANO-1,2,4,5-TETRAZINE WITH TETRATHIAFULVALENE [J].