ELECTRON SPIN RESONANCE OF HIGH-SPIN D5 SYSTEMS

被引：338
作者：
DOWSING, RD
GIBSON, JF
机构：
[1] Chemistry Department, Imperial College
[2] Physics Department, University of Keele, Staffordshire
来源：
JOURNAL OF CHEMICAL PHYSICS | 1969年 / 50卷 / 01期
关键词：
D O I：
10.1063/1.1670791
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The electron spin resonance spectra of polycrystalline samples of some sideramines (coprogen, ferrichrysin, ferricrocin, and ferrirubin), transferrin, and conalbumin are reported both at 9.3 and 36 kMc/sec and at various temperatures. These results have been interpreted in terms of a spin Hamiltonian of the form ℋ=gβH·S+D[S82-1/3(S+1)] +E(Sx2-Sv2). The application of this interpretation to other high-spin d5 systems both in single-crystal and polycrystalline form is discussed.
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页码：294 / &
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