ELECTRON SPIN RESONANCE OF HIGH-SPIN D5 SYSTEMS

被引：338

作者：

DOWSING, RD

GIBSON, JF

机构：

[1] Chemistry Department, Imperial College

[2] Physics Department, University of Keele, Staffordshire

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 50卷 / 01期

关键词：

D O I：

10.1063/1.1670791

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electron spin resonance spectra of polycrystalline samples of some sideramines (coprogen, ferrichrysin, ferricrocin, and ferrirubin), transferrin, and conalbumin are reported both at 9.3 and 36 kMc/sec and at various temperatures. These results have been interpreted in terms of a spin Hamiltonian of the form ℋ=gβH·S+D[S82-1/3(S+1)] +E(Sx2-Sv2). The application of this interpretation to other high-spin d5 systems both in single-crystal and polycrystalline form is discussed.

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页码：294 / &

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