THE VISIBLE-LIGHT INDUCED REARRANGEMENT OF A MANGANESE(III) COMPLEX OF AN UNSYMMETRICAL TETRADENTATE SCHIFF-BASE LIGAND, 4-[2-(2-HYDROXYPHENYLMETHYLENEAMINO)ETHYLAMINO]PENT-3-EN-2-ONE, TO A MANGANESE(III) COMPLEX OF THE SYMMETRICAL LIGAND SALEN

被引：58

作者：

GARCIADEIBE, A

SOUSA, A

BERMEJO, MR

MACRORY, PP

MCAULIFFE, CA

PRITCHARD, RG

HELLIWELL, M

机构：

[1] UNIV SANTIAGO DE COMPOSTELA,FAC QUIM,DEPT QUIM INORGAN,SANTIAGO,SPAIN

[2] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT CHEM,MANCHESTER M60 1QD,LANCS,ENGLAND

[3] UNIV MANCHESTER,DEPT CHEM,MANCHESTER M13 9PL,LANCS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 10期

关键词：

D O I：

10.1039/c39910000728

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Visible light irradiation of [{Mn(L)(H2O)}2](ClO4)2.4H2O, which contains the tetradentate unsymmetric Schiff's dianionic ligand 4-[2-(2-hydroxphenylmethyleneamino)ethylamino]pent-3-en-2-one, results in the formation of the dimeric [{Mn(salen)(H2O)}2](ClO4)2.H2O, which contains the symmetrical dianionic Schiff's base ligand N,N'-bis(salicylidene)ethylenediaminato; the X-ray crystal structure of the latter complex is reported.

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页码：728 / 729

页数：2

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