METAL-COMPLEXES OF BREDT OLEFINS - SYNTHESIS AND STRUCTURE OF BICYCLO[4.2.1]NON-1(8)-ENEBIS(TRIPHENYL-PHOSPHANE)PLATINUM(0)

被引：23
作者：
STAMM, E
BECKER, KB
ENGEL, P
ERMER, O
KEESE, R
机构：
[1] UNIV BERN,INST ORGAN CHEM,CH-3012 BERN,SWITZERLAND
[2] UNIV BERN,INST MINERAL PETROG,CH-3012 BERN,SWITZERLAND
[3] UNIV BASEL,INST ORGAN CHEM,CH-4056 BASEL,SWITZERLAND
[4] RUHR UNIV BOCHUM,CHEM ABT,D-4630 BOCHUM,FED REP GER
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 09期
关键词：
D O I：
10.1002/anie.197906851
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reversible stabilization of a Bredt olefin has been accomplished for the first time with a platinum(0) compound. In complex 3 (X‐ray structure analysis) the olefin has the same conformation as free 2 (force field calculations). Treatment of the complex with CS2 regenerates isomer‐free 2. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany
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页码：685 / 686
页数：2
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