B-[3-((DIISOPROPYLAMINO)DIMETHYLSILYL)ALLYL]DIISOPINOCAMPHEYLBORANE - AN EXCELLENT REAGENT FOR THE STEREOSELECTIVE SYNTHESIS OF ANTI VICINAL DIOLS

被引：62

作者：

BARRETT, AGM

MALECHA, JW

机构：

[1] Department of Chemistry, Colorado State University, Fort Collins

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 18期

关键词：

D O I：

10.1021/jo00018a004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aldehydes reacted stereoselectively with B-[3-((diisopropylamino)dimethylsilyl)allyl]diisopinocampheylborane, derived from (+)- and (-)-alpha-pinene, to provide, on workup with hydrogen peroxide, (3S,4R)- and (3R,4S)-dihydroxy-1-alkenes, respectively.

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页码：5243 / 5245

页数：3

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