ETHANE DEHYDROGENATION USING A HIGH-TEMPERATURE CATALYTIC MEMBRANE REACTOR

被引：81

作者：

GOBINA, E ^{[1
]}

HUGHES, R ^{[1
]}

机构：

[1] UNIV SALFORD,DEPT CHEM ENGN,SALFORD M5 4WT,LANCS,ENGLAND

来源：

JOURNAL OF MEMBRANE SCIENCE | 1994年 / 90卷 / 1-2期

关键词：

CATALYTIC DEHYDROGENATION; METAL MEMBRANES; MEMBRANE REACTORS; GAS SEPARATIONS;

D O I：

10.1016/0376-7388(94)80030-8

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Experiments have been conducted for the dehydrogenation of ethane to ethylene using a high-temperature catalytic membrane reactor under isothermal conditions. Typically, conversions of up to 7 times (cocurrent mode) and 8 times (countercurrent mode) higher than the equilibrium value achievable in conventional fixed-bed reactors have been attained at high sweep flow rates. The membrane used in this study was a thin layer of Pd-23 wt% Ag on porous Vycor glass. The significant improvement in the ethane conversion is attributed to the exclusive and continuous permeation of hydrogen through the membrane.

引用

页码：11 / 19

页数：9

共 30 条

[1]

ACKERMAN FJ, 1972, J CHEM ENG DATA, V17, P51, DOI 10.1021/je60052a011

[2] CATALYSIS WITH PERMSELECTIVE INORGANIC MEMBRANES [J].

ARMOR, JN .

APPLIED CATALYSIS, 1989, 49 (01) :1-25

[3]

BENNETT CO, 1982, MOMENTUM HEAT MASS T, P557

[4]

BITTER JGA, 1986, Patent No. 8629135

[5] DIFFUSION OF HYDROGEN AND DEUTERIUM IN PALLADIUM AND PD ALLOYS .I. GAS VOLUMETRIC MEASUREMENTS [J].

BOHMHOLDT, G ;

WICKE, E .

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1967, 56 (3-4) :133-+

[6]

CANNON KC, 1992, J MEMBRANE SCI, V65, P259

[7] FUEL CLEANUP SYSTEM - POISONING OF PALLADIUM-SILVER MEMBRANES BY GASEOUS IMPURITIES [J].

CHABOT, J ;

LECOMTE, J ;

GRUMET, C ;

SANNIER, J .

FUSION TECHNOLOGY, 1988, 14 (02) :614-623

[8] A HIGH-TEMPERATURE CATALYTIC MEMBRANE REACTOR FOR ETHANE DEHYDROGENATION [J].

CHAMPAGNIE, AM ;

TSOTSIS, TT ;

MINET, RG ;

WEBSTER, IA .

CHEMICAL ENGINEERING SCIENCE, 1990, 45 (08) :2423-2429

[9]

CHANG HN, 1991, MEMBRANE BIOREACTORS, V44, P27

[10]

GOBINA E, UNPUB DEV CHEM ENG M

← 1 2 3 →