REACTION OF N-DICHLOROMETHYLENE-N,N-DIMETHYLAMMONIUM CHLORIDE (VIEHES SALT) WITH HYDROXY COMPOUNDS - SYNTHESIS OF CARBONATES AND THIOCARBONATES

被引：12

作者：

COPELAND, C ^{[1
]}

STICK, RV ^{[1
]}

机构：

[1] UNIV WESTERN AUSTRALIA,DEPT ORGAN CHEM,NEDLANDS 6009,W AUSTRALIA,AUSTRALIA

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1979年 / 32卷 / 03期

关键词：

D O I：

10.1071/CH9790637

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of Viehe's salt (Me2N+=CCl2 Cl-) with benzene-1, 2-diol, phenol, 2, 3-dimethylbutane-2, 3-diol and trans-cyclohexane-1, 2-diol gives stable salts which may be readily converted into the corresponding carbonates and thiocarbonates. Both cis- and trans-cyclohexane-1, 2-diol give salts which rearrange, albeit at different rates, to the same trans chloro carbamate. © 1979 Australian Journal of Chemistry. All rights reserved.

引用

页码：637 / 641

页数：5

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