HIGHLY CHEMOSELECTIVE REACTIONS OF ZIRCONACYCLOPENTENES FOR SELECTIVE FUNCTIONALIZATION

被引：33

作者：

TAKAHASHI, T ^{[1
]}

AOYAGI, K ^{[1
]}

HARA, R ^{[1
]}

SUZUKI, N ^{[1
]}

机构：

[1] GRAD UNIV ADV STUDIES,OKAZAKI 444,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 13期

关键词：

D O I：

10.1039/c39930001042

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alcoholysis of zirconacyclopentenes proceeds at the alkyl carbon on Zr with high chemoselectivity in sharp contrast to monoiodination of zirconacyclopentenes with iodine; alcoholysis followed by iodination of zirconacyclopentenes produces stereodefined trisubstituted alkenyl iodides in high yields with high isomeric purities.

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页码：1042 / 1044

页数：3

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