SYNTHESIS AND CHARACTERIZATION OF NONA-OSMIUM CARBONYL CLUSTERS - CRYSTAL AND MOLECULAR-STRUCTURE OF [(PH3P)2N][OS9H(CO)24]

被引：14

作者：

AMOROSO, AJ ^{[1
]}

JOHNSON, BFG ^{[1
]}

LEWIS, J ^{[1
]}

RAITHBY, PR ^{[1
]}

WONG, WT ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 12期

关键词：

D O I：

10.1039/c39910000814

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The anion [Os9H(CO)24]-, 2 has been isolated in moderate yield by the vacuum pyrolysis of [Os3(CO)10(NCMe)2], and has been shown by a single crystal X-ray structure analysis to contain the previously unobserved tricapped octahedral Os9 metal core.

引用

页码：814 / 815

页数：2

共 9 条

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