EFFICIENT STEREOSELECTIVE TOTAL SYNTHESIS OF DENTICULATIN-A AND DENTICULATIN-B

被引：34

作者：

ANDERSEN, MW

HILDEBRANDT, B

HOFFMANN, RW

机构：

[1] Fachbereich Chemie Der, Universität, Marburg, W-3550, Hans-Meerwei-Strasse

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 01期

关键词：

D O I：

10.1002/anie.199100971

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Five of the eight stereocenters of the denticulatin 1 were formed by stereoselective aldehyde allylboration. This approach allows an efficient synthesis of even complex molecules. Naturally occurring denticulatin is produced by Siphonaria, which are native to the tidal zones of the Indian Ocean and the Caribbean.

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页码：97 / 99

页数：3

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