IR-SPECTRA OF CATALYSTS AND ADSORBED MOLECULES .28. OXIDATION AND OXIDATIVE DEHYDROGENATION OF 1-BUTENE ON MAGNESIUM FERRITE CATALYSTS

被引：0

作者：

AMIRBEKOV, EN ^{[1
]}

ALIEV, FV ^{[1
]}

LAFER, LI ^{[1
]}

RUBINSHTEIN, AM ^{[1
]}

YAKERSON, VI ^{[1
]}

机构：

[1] ACAD SCI AZSSR,INST THEORET PROBLEMS CHEM TECHNOL,BAKU,AZSSR

来源：

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1979年 / 28卷 / 11期

关键词：

D O I：

10.1007/BF00951693

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1. Study has been made of the oxidative dehydrogenation and the oxidation to CO2 of 1-butene and mixtures of 1-butene and oxygen on carrier Al2O3 and MgO-Fe2O3, MgO-Al2O3, Fe2O3-Al2O3 and MgO-Fe2O3-Al2O3 catalysts. 2. It is suggested that surface π and π-allyl complexes appear as intermediates in the oxidative dehydrogenation of 1-butene. 3. The oxidation of 1-butene to CO2 proceeds through surface formate structures. © 1980 Plenum Publishing Corporation.

引用

页码：2250 / 2253

页数：4

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