IR-SPECTRA OF CATALYSTS AND ADSORBED MOLECULES .28. OXIDATION AND OXIDATIVE DEHYDROGENATION OF 1-BUTENE ON MAGNESIUM FERRITE CATALYSTS

被引：0
作者：
AMIRBEKOV, EN [1 ]
ALIEV, FV [1 ]
LAFER, LI [1 ]
RUBINSHTEIN, AM [1 ]
YAKERSON, VI [1 ]
机构：
[1] ACAD SCI AZSSR,INST THEORET PROBLEMS CHEM TECHNOL,BAKU,AZSSR
来源：
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1979年 / 28卷 / 11期
关键词：
D O I：
10.1007/BF00951693
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
1. Study has been made of the oxidative dehydrogenation and the oxidation to CO2 of 1-butene and mixtures of 1-butene and oxygen on carrier Al2O3 and MgO-Fe2O3, MgO-Al2O3, Fe2O3-Al2O3 and MgO-Fe2O3-Al2O3 catalysts. 2. It is suggested that surface π and π-allyl complexes appear as intermediates in the oxidative dehydrogenation of 1-butene. 3. The oxidation of 1-butene to CO2 proceeds through surface formate structures. © 1980 Plenum Publishing Corporation.
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页码：2250 / 2253
页数：4
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