POLYBUTADIENE GRAFTING AND CROSS-LINKING IN HIGH-IMPACT POLYSTYRENE BULK THERMAL-PROCESS

被引：39

作者：

PENG, FM

机构：

[1] Monsanto Chemical Company, Springfield, Massachusetts

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1990年 / 40卷 / 7-8期

关键词：

D O I：

10.1002/app.1990.070400717

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The grafting and the crosslinking of polybutadiene during the bulk thermal polymerization of high‐impact polystyrene were studied. The kinetic equations for these two reactions were derived by the use of the moments of the distribution functions. This kinetic model indicates that both the density of grafting and the degree of crosslinking increase with the increasing temperature of polymerization and, most significantly, with the increasing conversion of styrene. Copyright © 1990 John Wiley & Sons, Inc.

引用

页码：1289 / 1302

页数：14

共 42 条

[1] STRUCTURE AND PROPERTIES OF MICROCOMPOSITES AND MACROCOMPOSITES FROM BLOCK POLYMERS
AGGARWAL, SL
LIVIGNI, RA
[J]. POLYMER ENGINEERING AND SCIENCE, 1977, 17 (08) : 498 - 505
[2] BALLOVA GD, 1969, VYSOKOMOL SOEDIN A+, V11, P2080
[3] DISPERSION OF MICROGEL IN IMPACT POLYSTYRENE
BENDER, BW
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1965, 9 (08) : 2887 - &
[4] FREE-RADICAL GRAFTING OF MONOMERS TO POLYDIENES .2. KINETICS AND MECHANISM OF STYRENE GRAFTING TO POLYBUTADIENE
BRYDON, A
BURNETT, GM
CAMERON, GG
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1974, 12 (05) : 1011 - 1021
[5] FREE-RADICAL GRAFTING OF MONOMERS TO POLYDIENES .1. EFFECT OF REACTION CONDITIONS ON GRAFTING OF STYRENE TO POLYBUTADIENE
BRYDON, A
BURNETT, GM
CAMERON, GG
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1973, 11 (12) : 3255 - 3269
[6] BUCKNALL CB, 1977, TOUGHENED PLASTICS A, pCH4
[7] CHU G, 1985, HECHENG XIANGJIAO GO, V8, P119
[8] EFFECT OF STRUCTURE ON IMPACT STRENGTH OF RUBBER-REINFORCED POLYSTYRENE
CIGNA, G
MATARRESE, S
BIGLIONE, GF
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1976, 20 (08) : 2285 - 2295
[9] PARTICLE FORMATION DURING SYNTHESIS OF RUBBER MODIFIED POLY(STYRENE)
ECHTE, A
[J]. ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1977, 58 (FEB): : 175 - 198
[10] MORPHOLOGY OF RUBBER-MODIFIED POLYSTYRENE BASED ON STYRENE-BUTADIENE 3-BLOCK-COPOLYMERS
ECHTE, A
GAUSEPOHL, H
LUTJE, H
[J]. ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1980, 90 (OCT): : 95 - 108

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