(CYCLOPROPYLCARBONYL)METAL COMPLEXES

被引：31

作者：

BRUCE, MI

IQBAL, MZ

STONE, FGA

机构：

[1] Department of Inorganic Chemistry, The University, Bristol

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1969年 / 20卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)80101-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of remarkably stable cyclopropylcarbonyl complexes of manganese, rhenium, iron and iridium is described. Attempts to prepare σ-cyclopropyl complexes by decarbonylation reactions were not successful, little reaction occurring under most conditions described. Reaction between PPh3 and the manganese complex resulted in concomitant decarbonylation and ring-opening to give a π-allyl derivative, π-C3H5Mn(CO)3PPh3. © 1969.

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页码：161 / &

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