SYNTHESIS, STRUCTURE, AND 2 D-NMR STUDIES OF NOVEL CHIRAL (ETA-3-ALLYL)PALLADIUM(II) COMPLEXES CONTAINING THE BIDENTATE LIGAND SPARTEINE

被引：73

作者：

TOGNI, A ^{[1
]}

RIHS, G ^{[1
]}

PREGOSIN, PS ^{[1
]}

AMMANN, C ^{[1
]}

机构：

[1] SWISS FED INST TECHNOL,ANORGAN CHEM LAB,CH-8092 ZURICH,SWITZERLAND

来源：

HELVETICA CHIMICA ACTA | 1990年 / 73卷 / 03期

关键词：

D O I：

10.1002/hlca.19900730321

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel cationic allylpalladium (II) comp, exes containing the alkaloid (−)sparteine (1) as a bidentate ligand have been prepared. Two of them, [η3(cyclohex‐2‐enyl)] (sparteine)palladium(II) hexafluorophosphate([Pd(η3‐C6 H9)(sparteine)][PF6] 3b) and (sparteine)[η3‐(1,1,3‐triphenylallyl)] palladium (II) trifluorophosphate ([Pd(η3‐Ph2CCHCHPh)(sparteine)][sparteine)] [CF3SO3]; (3c) were characterized by X‐ray diffraction. The application of 2D‐NMR methods (COSY and NOESY)affords a correlation between the solid‐state and solution structures for complex 3c. Copyright © 1990 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：723 / 732

页数：10

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