SESQUITERPENOIDS OF WARBURGIA SPECIES .2. UGANDENSOLIDE AND UGANDENSIDIAL (CINNAMODIAL)

被引：61
作者：
BROOKS, CJW
DRAFFAN, GH
机构：
[1] Chemistry Department, University of Glasgow, Glasgow, Scotland
来源：
TETRAHEDRON | 1969年 / 25卷 / 14期
关键词：
D O I：
10.1016/0040-4020(69)80031-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Two crystalline sesquiterpenoids of drimane type, ugandensolide (I) and ugandensidial (II) have been isolated from the heartwood of Warburgia ugandensis Sprague (Canellaceae), and their structures determined. Ugandensidial proved to be identical with cinnamodial from Cinnamosma fragrans Baillon (Canellaceae). An interesting example of isomerization during GLC has been observed for the α-acetoxy-ketones (VII and XIV). © 1969.
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页码：2887 / &
相关论文
共 22 条
[1]   THE CONSTITUTION AND STEROCHEMISTRY OF DRIMENOL, A NOVEL BICYCLIC SESQUITERPENOID [J].
APPEL, HH ;
BROOKS, CJW ;
OVERTON, KH .
JOURNAL OF THE CHEMICAL SOCIETY, 1959, (NOV) :3322-3332
[2]   SESQUITERPENOIDS .2. THE CONSTITUTION AND STEREOCHEMISTRY OF DRIMENIN, ISODRIMENIN, AND CONFERTIFOLIN [J].
APPEL, HH ;
CONNOLLY, JD ;
OVERTON, KH ;
BOND, RPM .
JOURNAL OF THE CHEMICAL SOCIETY, 1960, (NOV) :4685-4692
[3]   STRUCTURE OF POLYGODIAL - A NEW SESQUITERPENE DIALDEHYDE FROM POLYGONUM HYDROPIPER L [J].
BARNES, CS ;
LODER, JW .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1962, 15 (02) :322-&
[4]  
BHACCA NS, 1964, APPLICATIONS NMR SPE
[5]   INFRARED STUDIES WITH TERPENOID COMPOUNDS .2. CARBONYL ABSORPTIONS OF GAMMA-LACTONES [J].
BOND, RPM ;
CAIRNS, T ;
CONNOLLY, JD ;
EGLINTON, G ;
OVERTON, KH .
JOURNAL OF THE CHEMICAL SOCIETY, 1965, (JUL) :3958-&
[6]   RESEARCHES ON ACETYLENIC COMPOUNDS .1. THE PREPARATION OF ACETYLENIC KETONES BY OXIDATION OF ACETYLENIC CARBINOLS AND GLYCOLS [J].
BOWDEN, K ;
HEILBRON, IM ;
JONES, ERH ;
WEEDON, BCL .
JOURNAL OF THE CHEMICAL SOCIETY, 1946, (JAN) :39-45
[7]   CHARACTERIZATION OF 1,2- AND 1,3-DIOLS BY GAS CHROMATOGRAPHY-MASS SPECTROMETRY OF CYCLIC BORONATE ESTERS [J].
BROOKS, CJW ;
WATSON, J .
CHEMICAL COMMUNICATIONS, 1967, (18) :952-&
[8]   SESQUITERPENOIDS OF WARBURGIA SPECIES .I. WARBURGIN AND WARBURGIADIONE [J].
BROOKS, CJW ;
DRAFFAN, GH .
TETRAHEDRON, 1969, 25 (14) :2865-&
[9]  
CALZADILLA CH, 1968, 5 INT S CHEM NAT PRO
[10]  
CANONICA L, 1967, TETRAHEDRON LETT, P2137
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