REDOX PROPERTIES AND CATALYTIC PERFORMANCE OF COMPLEX OXIDES IN OXIDATIVE COUPLING OF METHANE

被引:2
|
作者
SINEV, MY
BYCHKOV, VY
KORCHAK, VN
TULENIN, YP
FATTAKHOVA, ZT
KALASHNIKOVA, OV
机构
[1] Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 117334
关键词
D O I
10.1016/0920-5861(94)80158-4
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The redox properties of model Mn-containing mixed oxide are studied. It is shown that water evolution can determine the rate of oxide reduction. The kinetic model of the redox process taking into account surface interactions and diffusion of oxygen, hydrogen and hydroxy ions in the oxide lattice can describe successfully the experimental data. The influence of slow water evolution on catalytic performance of the oxides in oxidative coupling of methane is discussed.
引用
收藏
页码:371 / 376
页数:6
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