SOLVENT SOLUTE AND SOLUTE SOLUTE INTERACTIONS FROM NMR IN NEMATIC PHASES

被引：2
|
作者：
KHETRAPAL, CL
SURYAPRAKASH, N
机构：
[1] Indian Institute of Science, Bangalore
来源：
LIQUID CRYSTALS | 1993年 / 14卷 / 05期
关键词：
D O I：
10.1080/02678299308026460
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The use of NMR spectroscopy of molecules oriented in liquid-crystalline media to study solvent-solute and solute-solute interactions in pi-systems such as benzene-chloroform and in charge transfer complexes, for example pyridine-iodine, is illustrated. Changes in molecular order and chemical shifts as a result of complexation are employed in such studies. The extraordinary symmetry of C60 has also been investigated by using a mixture of liquid crystals of opposite diamagnetic anisotropies indicating, thereby, negligible solvent-solute/solute-solute interactions.
引用
收藏
页码：1479 / 1484
页数：6
相关论文
共 50 条
  • [1] The role of solute conformation, solvent-solute and solute-solute interactions in crystal nucleation
    Li, Xin
    Wang, Na
    Huang, Yunhai
    Xing, Jiangna
    Huang, Xin
    Ferguson, Steven
    Wang, Ting
    Zhou, Lina
    Hao, Hongxun
    AICHE JOURNAL, 2023, 69 (08)
  • [2] SOLUTE-SOLVENT INTERACTIONS WITHIN NEMATIC MESOPHASE
    LUCKHURST, GR
    SETAKA, M
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1973, 19 (3-4) : 279 - 294
  • [3] Effect of solute-solute and solute-solvent interactions on the kinetics of nucleation in liquids
    Ruckenstein, Eli
    Berim, Gersh O.
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2010, 342 (02) : 528 - 539
  • [4] SPECIFIC SOLUTE-SOLUTE AND SOLUTE-SOLVENT INTERACTIONS IN ORGANIC SOLUTIONS OF INDOLE
    CAZEAUDU.C
    DUPY, F
    MARTINAU.M
    CHEMICAL PHYSICS LETTERS, 1973, 23 (03) : 397 - 399
  • [5] NMR RELAXATION STUDIES OF SOLUTE-SOLVENT INTERACTIONS
    BRYANT, RG
    ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1978, 29 : 167 - 188
  • [6] Microscopic aspects of solute-solute interactions induced by the solvent
    Bruge, F
    Cottone, G
    Noto, R
    Fornili, ZL
    JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1996, 93 (10) : 1858 - 1878
  • [7] Microscopic aspects of solute-solute interactions induced by the solvent
    J Chim Phys Phys Chim Biol, 10 (1858):
  • [8] Effects of solute-solvent and solvent-solvent attractive interactions on solute diffusion
    Yamaguchi, T
    Kimura, Y
    MOLECULAR PHYSICS, 2000, 98 (19) : 1553 - 1563
  • [9] Solute–Solute and Solute–Solvent Interactions in the Ternary LiCl + Sucrose + Water System at 298.15 K
    Vahideh Masumi
    Rahman Salamat-Ahangari
    Journal of Solution Chemistry, 2020, 49 : 1208 - 1224
  • [10] Solute NMR study of a bimesogenic liquid crystal with two nematic phases
    Dong, R. Y.
    Kohlmeier, A.
    Tamba, M. G.
    Mehl, G. H.
    Burnell, E. E.
    CHEMICAL PHYSICS LETTERS, 2012, 552 : 44 - 48
12345