CONDUCTIVITY OF D2O AND MICROMOLAR DNO3 IN D2O FROM 0 TO 100-DEGREES-C

被引：6

作者：

BAUMANN, EW

机构：

[1] Savannah River Technology Center, Westinghouse Savannah River Company, Aiken

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1993年 / 38卷 / 01期

关键词：

D O I：

10.1021/je00009a003

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Electrical conductivity values for D2O and for dilute nitric acid in D2O from 0 to 100-degrees-C were calculated using literature values of ionic and molar conductances, dissociation constants, densities, and viscosities. The concentration of DNO3 covered the pD (15) range of 4.5-7.4 at 25-degrees-C. Computations were validated by the agreement between calculated conductivities of the DNO3 system at pD 7.4 (near-neutral) and those for D2O. Walden's rule was only marginally followed, as would be expected for solvated anions and cations.

引用

页码：12 / 15

页数：4

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