CONDUCTIVITY OF D2O AND MICROMOLAR DNO3 IN D2O FROM 0 TO 100-DEGREES-C

被引：6
|
作者：
BAUMANN, EW
机构：
[1] Savannah River Technology Center, Westinghouse Savannah River Company, Aiken
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1993年 / 38卷 / 01期
关键词：
D O I：
10.1021/je00009a003
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Electrical conductivity values for D2O and for dilute nitric acid in D2O from 0 to 100-degrees-C were calculated using literature values of ionic and molar conductances, dissociation constants, densities, and viscosities. The concentration of DNO3 covered the pD (15) range of 4.5-7.4 at 25-degrees-C. Computations were validated by the agreement between calculated conductivities of the DNO3 system at pD 7.4 (near-neutral) and those for D2O. Walden's rule was only marginally followed, as would be expected for solvated anions and cations.
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页码：12 / 15
页数：4
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