SELF-ASSEMBLY OF A CU4 COMPLEX WITH COPLANAR COPPER(I) IONS - SYNTHESIS, STRUCTURE, AND ELECTROCHEMICAL PROPERTIES

被引：194

作者：

YOUINOU, MT

RAHMOUNI, N

FISCHER, J

OSBORN, JA

机构：

[1] Laboratoire de Chimie des Métaux de Transition et de Catalyse Université Louis Pasteur, Strasbourg, F-67000, 4, rue Blaise Pascal

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 06期

关键词：

D O I：

10.1002/anie.199207331

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pi-stacking interactions in the nearly parallel 3,6-bis(2-pyridyl)-pyridazine (dppn) ligands probably account for the distortion of the planar Cu4 unit in 1 from a square to a rhombus. Each Cu atom is surrounded in a tetrahedral fashion by two N atoms from pyridine and two N atoms from pyridazine units; the chelate rings themselves are planar. The distance between the pairs of dppn ligands is 3.47 angstrom.

引用

页码：733 / 735

页数：3