EXPERIMENTS ON THE HOMO-LUMO NATURE OF METAL-METAL BONDS

被引:57
作者
BEURICH, H [1 ]
MADACH, T [1 ]
RICHTER, F [1 ]
VAHRENKAMP, H [1 ]
机构
[1] UNIV FREIBURG,CHEM LAB,D-7800 FREIBURG,FED REP GER
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 09期
关键词
D O I
10.1002/anie.197906901
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electrochemical, X‐ray, and ESR studies on the metal‐metal interaction in the clusters 1 and 2, R = C6H5, lead to consistent results and confirm the significant energetic separation of the MM and the Mligand bond. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany
引用
收藏
页码:690 / 691
页数:2
相关论文
共 9 条
[2]   HETERONUCLEAR CLUSTER SYSTEMS .12. SYNTHESIS OF MU-PHENYLPHOSPHINEDIYL-BIS(TETRACARBONYLCOBALT) AND 1,1,1,2,2,2,3,3,3-NONACARBONYL-MU-3-PHENYLPHOSPHINEDIYL-TRIANGULO-DICOBALTIRON [J].
BURT, JC ;
SCHMID, G .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1978, (10) :1385-1387
[3]   MOLECULAR ORBITAL CALCULATIONS FOR COMPLEXES OF HEAVIER TRANSITION ELEMENTS .3. METAL-METAL BONDING AND ELECTRONIC STRUCTURE OF RE2CL82- [J].
COTTON, FA ;
HARRIS, CB .
INORGANIC CHEMISTRY, 1967, 6 (05) :924-&
[4]   PARAMAGNETIC PHOSPHIDO COBALT CARBONYL CLUSTERS [J].
MARKO, L ;
MARKO, B .
INORGANICA CHIMICA ACTA, 1975, 14 (02) :L39-L39
[5]   NEW HETERONUCLEAR CLUSTER WITH FECO2-FRAMEWORK AND FEMOCO-FRAMEWORK [J].
RICHTER, F ;
BEURICH, H ;
VAHRENKAMP, H .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 166 (01) :C5-C8
[6]   ORGANOMETALLIC CHALCOGEN COMPLEXES .21. STEROCHEMICAL ANALYSIS OF MIXED-METAL FECO2(CO)9S CLUSTER SYSTEM AND RESULTING BOND-LENGTH EVIDENCE FOR ANTIBONDING TRIMETAL CHARACTER OF UNPAIRED ELECTRON IN ISOSTRUCTURAL CO3(CO)9S CLUSTER SYSTEM [J].
STEVENSON, DL ;
WEI, CH ;
DAHL, LF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (23) :6027-+
[7]  
STROUSE CE, 1969, DISCUSS FARADAY SOC, V47, P93
[8]   WHAT DO WE KNOW ABOUT METAL-METAL BOND [J].
VAHRENKAMP, H .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1978, 17 (06) :379-392
[9]  
Vahrenkamp H., 1978, ANGEW CHEM, V90, P403