ELECTROSTATIC PERSISTENCE LENGTH OF WORMLIKE POLYELECTROLYTE

被引:0
|
作者
KOYAMA, R [1 ]
机构
[1] KYOTO UNIV,COLL LIBERAL ARTS & SCI,DEPT PHYS,KYOTO 606,JAPAN
关键词
POLYELECTROLYTE; POLYMER SOLUTION; WORMLIKE CHAIN; PERSISTENCE LENGTH; EXCLUDED VOLUME EFFECT;
D O I
10.1143/JPSJ.61.1899
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The electrostatic persistence length of wormlike polyelectrolyte in a salt-free solution is calculated using its molecular scattering factor in a more accurate form than in the previous paper. The calculated persistence length becomes a=6-1R0f/(1 - f) (0<<f<1), where R0 is a distance within which two monomers of different molecular segments are assumed not to be close to each others owing to the strong electrostatic repulsion between the segments, and f is a constant smaller than unity but close to it. When the value 1 - f is very small compared with unity, and is neglected, this result coincides with that obtained in another paper considering the excluded volume effect.
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页码:1899 / 1902
页数:4
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