TRANSITION-METAL FULVENE COMPLEXES .14. CRYSTAL AND MOLECULAR-STRUCTURE OF FERROCENYLDIPHENYLCARBENIUM TETRAFLUOROBORATE - FULVENE-IRON COMPLEX

被引：139

作者：

BEHRENS, U

机构：

[1] Institut für Anorganische, Angewandte Chemie der Universität Hamburg, D 2000 Hamburg 13

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 182卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)85878-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure of ferrocenyldiphenylcarbenium tetrafluoroborate has been determined by single crystal X-ray analysis. The compound crystalizes in the orthorhombic space group P21cn with lattice constants a 905.1(3), b 1087.0(7), c 1964.4(9) pm; Z 4. The final R index for 1525 observed reflections of non-zero weight (F ≫ 2 σ) is 0.040. The molecule can be described as a fulvenecyclopentadienyliron cation with the fulvene exocyclic double bond bent to the iron (angle 20.7°) and an FeCexo distance of 271.5 pm. © 1979.

引用

页码：89 / 98

页数：10

共 19 条

[1]

ALLENMAR.S, 1974, TETRAHEDRON LETT, P371

[2]

Andrianov V. G., 1975, CHEM COMMUN, P117, DOI 10.1039/C39750000117

[3]

ANDRIANOV VG, 1977, ZH STRUKT KHIM, V18, P318

[4]

Cais M, 1966, ORGANOMET CHEM REV, V1, P435