1-(4-Chlorophenyl)-2-[tris(4-methylphenyl)-lambda(5)-phosphanylidene]butane-1,3dione

被引：0

作者：

Sabounchei, Seyyed Javad ^{[1
]}

Shahriary, Parisa ^{[1
]}

Fashami, Faegheh Hosseini ^{[1
]}

Morales-Morales, David ^{[2
]}

Hernandez-Ortega, Simon ^{[2
]}

机构：

[1] Bu Ali Sina Univ, Fac Chem, Hamadan 65174, Iran

[2] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷

关键词：

single-crystal X-ray study; T = 298 K; mean sigma(C-C)= 0.003 A(degrees); R factor = 0.040; wR factor = 0.099; data-to-parameter ratio = 14.9;

D O I：

10.1107/S1600536812051689

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title ylide, C31H28ClO2P [ common name alpha- acetyl-alpha-p-chlobenzoylmethylenetri( p-tolyl) phosphorane], the dihedral angle between the 4-chlorophenyl ring and that of the ylide moiety is 66.15 (10) (degrees). The geometry around the P atom is slightly distorted tetrahedral [angle range = 105.22 (8)115.52 (9)(degrees) ] and the carbonyl O atoms are syn-oriented with respect to the P atom. The ylide group is close to planar [maximum deviation from the least-squares= 0.006 (2) A(degrees) and the P-C, C-C and C=O bond lengths are consistent with electron delocalization involving the O atoms.

引用

页码：O183 / +

页数：9

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