RHEOLOGY OF NON-NEWTONIAN GLASS-FORMING MELTS .2. KINETICS OF RELAXATION AND RETARDATION

被引:14
作者
GUTZOW, I [1 ]
DOBREVA, A [1 ]
SCHMELZER, J [1 ]
机构
[1] UNIV ROSTOCK,SEKT PHYS,O-2500 ROSTOCK,GERMANY
关键词
D O I
10.1007/BF00400872
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A general formalism describing the kinetics of relaxation and retardation in glass-forming materials is developed. By introducing the real flow behaviour of a particular system into an extended analogue of Maxwell's equation, a set of non-linear relaxational and retardational dependences, applicable to liquids with different structures, is obtained. The Kohlrausch stretched-exponent formula and similar dependences with time-dependent relaxation times are also derived. A comparison with established empirical relations and existing experimental data gives satisfactory coincidence.
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页码:901 / 908
页数:8
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