PROTON NMR ASSIGNMENTS FOR CHOLESTEROL - USE OF DEUTERIUM NMR AS AN ASSIGNMENT AID

被引：20

作者：

SAWAN, SP ^{[1
]}

JAMES, TL ^{[1
]}

GRUENKE, LD ^{[1
]}

CRAIG, JC ^{[1
]}

机构：

[1] UNIV CALIF SAN FRANCISCO,SCH PHARM,DEPT PHARMACEUT SCI,SAN FRANCISCO,CA 94143

来源：

JOURNAL OF MAGNETIC RESONANCE | 1979年 / 35卷 / 03期

基金：

美国国家卫生研究院; 美国国家科学基金会;

关键词：

D O I：

10.1016/0022-2364(79)90063-5

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

The 360-MHz proton magnetic resonance spectra of cholesterol and 2,2,4,4,6cholesterol-d5 and the 15-MHz deuterium NMR spectrum of the deuterated compound have been recorded. The combination of these two NMR frequencies, as well as double-resonance experiments, permitted the unambiguous assignments for the chemical shifts of the A and B ring protons. © 1979.

引用

页码：409 / 413

页数：5

共 8 条

[1]

BARRY CD, 1973, NUCL MAGN RESON, P173

[2] TRIS(DIPIVALOMETHANATO)EUROPIUM(III) - A SHIFT REAGENT FOR USE IN PROTON MAGNETIC RESONANCE ANALYSIS OF STEROIDS AND TERPENOIDS [J].

DEMARCO, PV ;

ELZEY, TK ;

LEWIS, RB ;

WENKERT, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (19) :5737-+

[3]

DIEHL P, 1974, NUCL MAGN RESON, P275

[4]

GRUENKE LD, UNPUBLISHED

[5] PARAMAGNETIC SHIFTS IN SOLUTIONS OF CHOLESTEROL AND DIPYRIDINE ADDUCT OF TRISDIPIVALOMETHANATOEUROPIUM(3) . A SHIFT REAGENT [J].

HINCKLEY, CC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (18) :5160-&

[6] DEUTERIUM MAGNETIC-RESONANCE, APPLICATIONS IN CHEMISTRY, PHYSICS AND BIOLOGY [J].

MANTSCH, HH ;

SAITO, H ;

SMITH, ICP .

PROGRESS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY, 1977, 11 :211-271

[7] SOLUTION CONFORMATION OF NICOTINE - H-1 AND H-2 NUCLEAR MAGNETIC-RESONANCE INVESTIGATION [J].

PITNER, TP ;

EDWARDS, WB ;

BASSFIELD, RL ;

WHIDBY, JF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (01) :246-251

[8]

1974, ITRCAL ITERATION CAL

← 1 →