FREE-RADICAL ADDITION OF SUCCINIC ANHYDRIDE TO OLEFINS AND ALKYL ALLYL ETHERS

被引:0
作者
OGIBIN, YN
ELINSON, MN
NIKISHIN, GI
机构
[1] N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow
来源
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1979年 / 28卷 / 07期
关键词
D O I
10.1007/BF00947335
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
1. Replacing the hydrogen, atoms of the vinyl grouping in 1-alkenes by alkyl groups substantially lowers the ability of the olefins to form the 1:1 adducts with succinic anhydride in the free-radical addition reaction. 2. The free-radical addition of succinic anhydride to 2-ethyl-1-hexene, 2-octene, and the hexyl and octyl allyl ethers (initiator=tert-butyl peroxide), respectively, gave the 2-ethylhexyl-, 1-methylheptyl- and 1-ethylhexyl-(1:1 mixture), and 4-oxadecyl-, and 4-oxadodecylsuccinic anhydrides. © 1980 Plenum Publishing Corporation.
引用
收藏
页码:1504 / 1506
页数:3
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