Catalytic Activity of Commercial Metal Catalysts on the Combustion of Low-concentration Methane

被引:0
|
作者
Lee, Kyong-Hwan [1 ]
Park, Jae-Hyun [1 ]
Song, Kwang-Sup [2 ]
机构
[1] KIER, Fossil Energy Environm Res Dept, Daejeon, South Korea
[2] Adv Energy Mat Res Dept, Daejeon, South Korea
关键词
Methane combustion; Commercial metal catalysts; Activity; Kinetics;
D O I
暂无
中图分类号
P4 [大气科学(气象学)];
学科分类号
0706 ; 070601 ;
摘要
This study was focused on the catalytic activity for the combustion of low - concentration methane using various commerical catalysts (six transition metal catalysts in Russia and one rare earth metal (Honeycomb) catalyst in Korea). Catalytic activity was strongly influenced by the type and loading content of metal supported in catalyst. Catalytic performance showed the highest activity in Honeycomb catalyst including rare earth metal, which was the most expensive catalyst, while the next was the catalyst supported Cu with high content (AOK-78-52) and also that supported Cr and Co (AOK-78-56). However, both AOK-78-52 and AOK-78-56 catalysts that were very cheap had lower activation energy than Honeycomb catalyst. In the economical field, both AOK-78-52 and AOK-78-56 catalysts with transition metals showed a good alternative catalyst on the combustion of methane.
引用
收藏
页码:625 / 630
页数:6
相关论文
共 8 条
  • [1] Oxidation of methane over palladium catalysts:: effect of the support
    Escandón, LS
    Ordóñez, S
    Vega, A
    Díez, FV
    [J]. CHEMOSPHERE, 2005, 58 (01) : 9 - 17
  • [2] Catalytic combustion of benzene over supported metal oxides catalysts
    Hong, SS
    Lee, GH
    Lee, GD
    [J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2003, 20 (03) : 440 - 444
  • [3] Catalytic combustion of methane over commercial catalysts in presence of ammonia and hydrogen sulphide
    Hurtado, P
    Ordóñez, S
    Vega, A
    Díez, FV
    [J]. CHEMOSPHERE, 2004, 55 (05) : 681 - 689
  • [4] Low-temperature methane oxidation over oxide-supported Pd catalysts:: inhibitory effect of water vapor
    Kikuchi, R
    Maeda, S
    Sasaki, K
    Wennerström, S
    Eguchi, K
    [J]. APPLIED CATALYSIS A-GENERAL, 2002, 232 (1-2) : 23 - 28
  • [5] Supported metal oxides for catalytic combustion of CO and VOCs emissions: Preparation of titania overlayers on a macroporous support
    Larsson, PO
    Berggren, H
    Andersson, A
    Augustsson, O
    [J]. CATALYSIS TODAY, 1997, 35 (1-2) : 137 - 144
  • [6] Catalytic oxidation of chlorinated benzenes over V2O5/TiO2 catalysts
    Lichtenberger, J
    Amiridis, MD
    [J]. JOURNAL OF CATALYSIS, 2004, 223 (02) : 296 - 308
  • [7] Characteristics of chromium oxides supported on TiO2 and Al2O3 for the decomposition of perchloroethylene
    Yim, SD
    Nam, IS
    [J]. JOURNAL OF CATALYSIS, 2004, 221 (02) : 601 - 611
  • [8] Study of the methane combustion and TPR/TPO properties of Pd/Ce-Zr-M/Al2O3 catalysts with M = Mg, Ca, Sr, Ba
    Yue, BH
    Zhou, RX
    Wang, YJ
    Zheng, XM
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 238 (1-2) : 241 - 249