Sulfated Zirconia Catalysts for Low Temperature Isomerization of n-Pentane

被引：0
|
作者：
Aboul-Gheit, A. K. [1 ]
El-Desouki, D. S. [1 ]
Abdel-Hamid, S. M. [1 ]
Ghoneim, S. A. [1 ]
Ibrahim, A. H. [1 ]
Gad, F. K. [2 ]
机构：
[1] Egyptian Petr Res Inst, Proc Dev Div, Cairo, Egypt
[2] Suez Canal Univ, Fac Petr & Minerals Engn, Ismailia, Egypt
来源：
EGYPTIAN JOURNAL OF CHEMISTRY | 2012年 / 55卷 / 05期
关键词：
Zirconium sulphate; Hydroisomerization; n-Pentane; Super acids; Sulfation and Sol-gel;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
NCONVENTIONAL sulphated zirconia (SZ) catalysts were prepared and examined for n-pentane isomerisation in this investigation. The sulfation was performed using H2SO4 acid. The calcination step seems to attain the highest influence using our sol-gel preparations, where the crystallinity transforms to the denser form. However, the surface properties do not exhibit such effectiveness. Calcination at 500 degrees C gives the best activities and stabilities, whereas at 650 degrees C, calcination is deteriorative. IR spectra, TPR, TGA, DSC, XRD and surface properties of the current catalysts were investigated.
引用
收藏
页码：509 / 527
页数：19
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