(Z)-3-(2-Methoxybenzyl)-1,5-benzothiazepin- 4(5H)-one

被引：4
|
作者：
Selvakumar, R. [1 ]
Bakthadoss, M. [1 ]
Lakshmanan, D. [2 ]
Murugavel, S. [3 ]
机构：
[1] Univ Madras, Dept Organ Chem, Madras 600025, Tamil Nadu, India
[2] C Abdul Hakeem Coll Engn & Technol, Dept Phys, Vellore 632509, Tamil Nadu, India
[3] Thanthai Periyar Govt Inst Technol, Dept Phys, Vellore 632002, Tamil Nadu, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
D O I：
10.1107/S160053681202661X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, C17H15NO2S, the seven-membered thiazepine ring adopts a distorted twist-boat conformation. The dihedral angle between the mean planes of the benzothiazepin ring system and the attached benzene ring is 47.7 (1)degrees. In the crystal, pairs of N-H center dot center dot center dot O hydrogen bonds link inversion-related molecules into dimers, generating R-2(2) (8) ring motifs. These dimers are further connected into a chain along the a axis by C-H center dot center dot center dot O hydrogen bonds, resulting in R-2(2) (14) ring motifs. The crystal packing also features C-H center dot center dot center dot pi interactions.
引用
收藏
页码：O2126 / +
页数：8
相关论文
共 50 条
  • [1] 3-(4-Methoxybenzyl)-1,5-benzothiazepin- 4(5H)-one
    Selvakumar, R.
    Bakthadoss, M.
    Vijayakumar, S.
    Murugavel, S.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O693 - +
  • [2] (Z)-3-(2-Chlorobenzyl)-1,5-benzothiazepin-4(5H)-one
    Sabari, V.
    Selvakumar, R.
    Bakthadoss, M.
    Aravindhan, S.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2283 - +
  • [3] (Z)-3-(4-Chlorobenzyl)-1,5-benzothiazepin-4(5H)-one
    Lakshmanan, D.
    Murugavel, S.
    Selvakumar, R.
    Bakthadoss, M.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2130 - +
  • [4] (Z)-3-(2,4-Dichlorobenzyl)-1,5-benzothiazepin-4(5H)-one
    Murugavel, S.
    Manikandan, N.
    Selvakumar, R.
    Bakthadoss, M.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O564 - +
  • [5] (Z)-3-(3,4-Dimethoxybenzyl)-1,5-benzothiazepin-4(5H)-one
    Selvakumar, R.
    Bakthadoss, M.
    Vijayakumar, S.
    Murugavel, S.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O708 - +
  • [6] 3-[(Z)-Benzylidene]-2,3-dihydro-1,5-benzothiazepin-4(5H)-one
    Sabari, V.
    Jagadeesan, G.
    Selvakumar, Raman
    Bakthadoss, Mannickam
    Aravindhan, S.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3061 - U1638
  • [7] (Z)-3-Benzyl-1,5-benzothiazepin-4(5H)-one
    Sabari, V.
    Selvakumar, R.
    Bakthadoss, M.
    Aravindhan, S.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : 02329 - +
  • [8] (Z)-3-(3,4-Dimethoxybenzylidene)-2,3dihydro-1,5-benzothiazepin-4(5H)-one
    Bakthadoss, M.
    Selvakumar, R.
    Manikandan, N.
    Murugavel, S.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O562 - +
  • [9] 3-(2-Methylbenzylidene)-2,3-dihydro-1,5-benzothiazepin-4(5H)-one
    Sridevi, D.
    Bhaskaran, Sundari
    Usha, G.
    Murugan, G.
    Bakthadoss, M.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O243 - U1272
  • [10] 2,3-dihydro-1,5-benzothiazepin-4(5H)-one
    Qin, BY
    Zhao, GL
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : O1831 - O1832
12345