Crystal structure of bis{N-[2-(dimethylamino) ethyl] quinolin-8-amine kappa N-3,N',N''} nickel(II) dichloride 3.5-hydrate

被引:0
作者
Kariuki, Benson M. [1 ]
Al-Sudani, Abdul-Razak H. [2 ]
机构
[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales
[2] Baghdad Univ Women, Coll Sci, Dept Chem, Baghdad, Iraq
关键词
crystal structure; N-[2-(dimethylamino)ethyl] quinolin-8-amine; nickel(II) complex; hydrogen bonding;
D O I
10.1107/S1600536814019035
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Ni(C13H17N3)(2)]Cl-2 center dot 3.5H(2)O,the geometry of the NiN6 complex cation is slightly distorted octahedral, with a facial arrangement of the two tridentate N-[2(dimethylamino) ethyl] quinolin-8-amine ligands around the metal ion. The asymmetric unit consists of two independent complex half-molecules located on centres of inversion, together with two chloride counter-anions and 3.5 water molecules of solvation, one of which is disordered across an inversion centre. In the crystal, O-H center dot center dot center dot O, O-H center dot center dot center dot Cl and N-H center dot center dot center dot Cl hydrogen-bonding interactions form a threedimensional network structure.
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页码:M339 / +
页数:12
相关论文
共 15 条
[1]   Dichlorido{8-[2-(dimethylamino)ethyl-amino]quinoline-kappa N-3,N ',N"}zinc [J].
Al-Sudani, Abdul-Razak H. .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 :M1-+
[2]  
ALSUDANI ARH, 2013, ACTA CRYSTALLOGRAP E, V0069
[3]   COMPLETION AND REFINEMENT OF CRYSTAL-STRUCTURES WITH SIR92 [J].
ALTOMARE, A ;
CASCARANO, G ;
GIACOVAZZO, C ;
GUAGLIARDI, A .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1993, 26 (pt 3) :343-350
[4]  
Cambridge Soft, 2001, CHEMDRAW ULTR
[5]   WinGX and ORTEP for Windows: an update [J].
Farrugia, Louis J. .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2012, 45 :849-854
[6]   Chiral tertiary diamines in asymmetric synthesis [J].
Kizirian, Jean-Claude .
CHEMICAL REVIEWS, 2008, 108 (01) :140-205
[7]   Mercury CSD 2.0 -: new features for the visualization and investigation of crystal structures [J].
Macrae, Clare F. ;
Bruno, Ian J. ;
Chisholm, James A. ;
Edgington, Paul R. ;
McCabe, Patrick ;
Pidcock, Elna ;
Rodriguez-Monge, Lucia ;
Taylor, Robin ;
van de Streek, Jacco ;
Wood, Peter A. .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2008, 41 :466-470
[8]   Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine -: X-ray crystal structure of the polymeric Cd(II) complex [J].
Miodragovic, Djenana U. ;
Mitic, Dragana M. ;
Miodragovic, Zoran M. ;
Bogdanovic, Goran A. ;
Vitnik, Zeljko J. ;
Vitorovic, Maja D. ;
Radulovic, Milanka D. ;
Nastasijevic, Branislav J. ;
Juranic, Ivan O. ;
Andelkovic, Katarina K. .
INORGANICA CHIMICA ACTA, 2008, 361 (01) :86-94
[9]  
*NON, 2000, COLLECT
[10]   Processing of X-ray diffraction data collected in oscillation mode [J].
Otwinowski, Z ;
Minor, W .
MACROMOLECULAR CRYSTALLOGRAPHY, PT A, 1997, 276 :307-326