PENTAORGANYLS OF ANTIMONY

被引:28
作者
HELLWINKEL, D
BACH, M
机构
关键词
D O I
10.1016/S0022-328X(00)88225-X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Some new spirocycles of pentacoordinated antimony are described. By means of the temperature-dependent proton-resonance spectra of the antimony penta- organyls (XXXV) and (XXXVI) conclusions concerning the dynamic stereochemistry of these derivatives are possible. The cyclic stibines, essential for the synthesis of the pentavalent antimony derivatives, are prepared by a new method with the aid of bidentate cadmium organyls. © 1969.
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页码:389 / +
页数:1
相关论文
共 43 条
[1]   A REINVESTIGATION OF CRYSTAL AND MOLECULAR STRUCTURE OF PENTAPHENYLANTIMONY [J].
BEAUCHAMP, AL ;
BENNETT, MJ ;
COTTON, FA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (24) :6675-+
[2]   Iodo derivatives of diphenyl ether I The mono- and certain diiodo-derivatives of diphenyl ether, and of 2-and 4-carboxy diphenyl ethers [J].
Brewster, RQ ;
Strain, F .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1934, 56 :117-120
[3]   THE CONFIGURATION OF HETEROCYCLIC COMPOUNDS .11. PREPARATION OF PHENOXSTIBINES AND RESOLUTION OF 10-PARA-CARBOXYPHENYL-2-METHYLPHENOXSTIBINE [J].
CAMPBELL, IGM .
JOURNAL OF THE CHEMICAL SOCIETY, 1947, (JAN) :4-10
[4]   SYNTHESIS OF SOME CYCLIC IODONIUM SALTS [J].
COLLETTE, J ;
MCGREER, D ;
CRAWFORD, R ;
CHUBB, F ;
SANDIN, RB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (15) :3819-3820
[5]   VIBRATIONAL SPECTRUM AND STRUCTURE OF PENTAMETHYLANTIMONY [J].
DOWNS, AJ ;
SCHMUTZL.R ;
STEER, IA .
CHEMICAL COMMUNICATIONS, 1966, (08) :221-&
[6]  
FRANZEN V, 1967, LIEBIGS ANN CHEM, V703, P90
[7]  
HEINEKEY DM, 1959, J CHEM SOC, P3101
[9]  
HELLWINKEL D, 1968, CHIMIA, V22, P488
[10]   ELECTROPHILIC AND NUCLEOPHILIC SUBSTITUTION REACTIONS WITH DERIVATIVES OF PENTA-COORDINATED ARSENIC [J].
HELLWINKEL, D ;
KILTHAU, G .
CHEMISCHE BERICHTE-RECUEIL, 1968, 101 (01) :121-+