(2E)-1-(4,4 ''-Difluoro-5 '-methoxy-1,1 ': 3 ',1 ''-terphenyl-4 '-yl)-3-[4-( methyl-sulfanyl) phenyl] prop-2-en-1-one

被引:1
作者
Kant, Rajni [1 ]
Gupta, Vivek K. [1 ]
Kapoor, Kamini [1 ]
Samshuddin, S. [2 ]
Narayana, B. [2 ]
机构
[1] Univ Jammu, Postgrad Dept Phys & Elect, X Ray Crystallog Lab, Jammu 180006, India
[2] Mangalore Univ, Dept Studies Chem, Mangalagangothri 574199, Karnataka, India
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词
data-to-parameter ratio = 15.0; mean σ(C-C) = 0.003 Å; R factor = 0.052; single-crystal X-ray study; T = 293 K; wR factor = 0.142;
D O I
10.1107/S1600536812030139
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C29H22F2O2S, the central benzene ring makes dihedral angles of 45.83 (7), 38.90 (7) and 55.50 (7)degrees with the two fluoro-substituted benzene rings and the methylsulfanyl- substituted benzene ring, respectively. In the crystal, C-H center dot center dot center dot O contacts connect the molecules into layers lying perpendicular to the c axis. In addition, pi-pi stacking interactions between one of the fluorophenyl groups [centroid-centroid distances = 3.681 (1) and 3.818 (1) angstrom] are observed.
引用
收藏
页码:02378 / +
页数:9
相关论文
共 10 条
  • [1] Farrugia L.J., 1997, J APPL CRYSTALLOGR, V30, P565, DOI [DOI 10.1107/S0021889897003117, 10.1107/S0021889897003117]
  • [2] 1-(4,4"-Difluoro-5′-methoxy-1,1′:3′,1"-terphenyl-4′-yl)ethanone
    Fun, Hoong-Kun
    Hemamalini, Madhukar
    Samshuddin, S.
    Narayana, B.
    Sarojini, B. K.
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : o163
  • [3] (2E)-1-(4,4 ''-Difluoro-5 '-methoxy-1,1 ':3 ',1 ''-terphenyl-4 '-yl)-3-(2-fluoro-phenyl)prop-2-en-1-one
    Fun, Hoong-Kun
    Loh, Wan-Sin
    Samshuddin, S.
    Narayana, B.
    Sarojini, B. K.
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2024 - +
  • [4] (E)-1-(4,4"-Difluoro-5′-methoxy-1,1′:3′,1"-terphenyl-4′-yl)-3-(6-methoxynaphthalen-2-yl)prop-2-en-1-one
    Fun, Hoong-Kun
    Hemamalini, Madhukar
    Samshuddin, S.
    Narayana, B.
    Sarojini, B. K.
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3327 - U1068
  • [5] Gill M, 1987, Fortschr Chem Org Naturst, V51, P1
  • [6] Natural terphenyls: Developments since 1877
    Liu, Ji-Kai
    [J]. CHEMICAL REVIEWS, 2006, 106 (06) : 2209 - 2223
  • [7] Oxford Diffraction, 2010, CRYSALIS PRO
  • [8] (E)-3-(2-Chlorophenyl)-1-(4,4 ''-difluoro-5 '-methoxy-1,1 ':3 ',1 ''-terphenyl-4 '-yl)prop-2-en-1-one
    Samshuddin, S.
    Narayana, Badiadka
    Yathirajan, Hemmige S.
    Betz, Richard
    Gerber, Thomas
    Hosten, Eric
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1538 - +
  • [9] A short history of SHELX
    Sheldrick, George M.
    [J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122
  • [10] Structure validation in chemical crystallography
    Spek, Anthony L.
    [J]. ACTA CRYSTALLOGRAPHICA SECTION D-STRUCTURAL BIOLOGY, 2009, 65 : 148 - 155