SELECTIVE CONDUCTION OF ALKALI-METAL IONS IN POLY(DIAZA-CROWN ETHER)

被引：7
|
作者：
OHNO, H [1 ]
YAMAZAKI, H [1 ]
TSUKUBE, H [1 ]
机构：
[1] OKAYAMA UNIV,COLL LIBERAL ARTS & SCI,DEPT CHEM,OKAYAMA 700,JAPAN
来源：
POLYMER | 1993年 / 34卷 / 07期
关键词：
POLY(CROWN ETHER); ION CONDUCTION; CATION SELECTIVITY; ALKALI METAL ION;
D O I：
10.1016/0032-3861(93)90874-A
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Poly(diaza-18-crown-6) (1) was mixed with alkali metal perchlorates (MClO4; M = Li, Na, K, Rb and Cs). Curved Arrhenius plots for ion conductivity were found for all dry samples, suggesting that ion migration occurs with segmental motion in 1. The potassium cation showed the lowest ion conductivity, reflecting a stronger interaction with the crown ether structure.
引用
收藏
页码：1533 / 1534
页数：2
相关论文
共 50 条
  • [31] ALKALI-METAL ION SPECIFICITY OF A CROWN ETHER PRECIPITATE WITH PHOSPHOMOLYBDIC ACID
    FERNANDO, LA
    MILES, ML
    BOWEN, LH
    RADIOCHEMICAL AND RADIOANALYTICAL LETTERS, 1979, 38 (5-6): : 387 - 394
  • [32] SELECTIVE COLUMN CONCENTRATION OF ALKALI-METAL CATIONS WITH A CROWN-ETHER CARBOXYLIC-ACID RESIN
    HAYASHITA, T
    LEE, JH
    CHEN, SP
    BARTSCH, RA
    ANALYTICAL CHEMISTRY, 1991, 63 (17) : 1844 - 1847
  • [33] COMPLEXES OF ALKALI-METAL IONS WITH POLY(ETHYLENE OXIDE)
    FENTON, DE
    PARKER, JM
    WRIGHT, PV
    POLYMER, 1973, 14 (11) : 589 - 589
  • [34] Solvent extraction of divalent transition metal ions with diaza-crown ethers having two acylpyrazolone moieties
    Umetani, Shigeo
    Ito, Makoto
    Shimojo, Shinichiro
    Kurahasi, Kensuke
    Yamazaki, Shoko
    Ogura, Kaoru
    SOLVENT EXTRACTION RESEARCH AND DEVELOPMENT-JAPAN, 2007, 14 : 177 - 181
  • [35] A NOVEL DIAZA-CROWN ETHER AND CRYPTANDS FROM GLUCOPYRANOSE AND THEIR COMPLEX-FORMING PROPERTIES
    BAKO, P
    FENICHEL, L
    TOKE, L
    LIEBIGS ANNALEN DER CHEMIE, 1990, (12): : 1161 - 1164
  • [36] Stability of crown-ether complexes with alkali-metal ions in ionic liquid-water mixed solvents
    K. Popov
    H. Rönkkömäki
    M. Hannu-Kuure
    T. Kuokkanen
    M. Lajunen
    A. Vendilo
    P. Oksman
    L. H. J. Lajunen
    Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2007, 59 : 377 - 381
  • [37] Stability of crown-ether complexes with alkali-metal ions in ionic liquid-water mixed solvents
    Popov, K.
    Ronkkomaki, H.
    Hannu-Kuure, M.
    Kuokkanen, T.
    Lajunen, M.
    Vendilo, A.
    Oksman, P.
    Lajunen, L. H. J.
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2007, 59 (3-4) : 377 - 381
  • [38] ALKALI-METAL ION-SELECTIVE ELECTRODES BASED ON BIS(CROWN ETHER) DERIVATIVES CONTAINING NITROGEN ATOM
    KIMURA, K
    OISHI, H
    SAKAMOTO, H
    SHONO, T
    NIPPON KAGAKU KAISHI, 1987, (03) : 277 - 282
  • [39] CROWN ETHER MODIFIED POLYETHYLENEIMINE SELECTIVE EXTRACTION OF ALKALI-METAL CATIONS FROM AQUEOUS TO ORGANIC-PHASE
    ANZAI, J
    SAKATA, Y
    UENO, A
    OSA, T
    MAKROMOLEKULARE CHEMIE-RAPID COMMUNICATIONS, 1982, 3 (06): : 399 - 403
  • [40] ANION EFFECT ON SELECTIVITY IN CROWN-ETHER EXTRACTION OF ALKALI-METAL CATIONS
    OLSHER, U
    HANKINS, MG
    KIM, YD
    BARTSCH, RA
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (08) : 3370 - 3371
12345