SELECTIVE CONDUCTION OF ALKALI-METAL IONS IN POLY(DIAZA-CROWN ETHER)

被引：7
|
作者：
OHNO, H [1 ]
YAMAZAKI, H [1 ]
TSUKUBE, H [1 ]
机构：
[1] OKAYAMA UNIV,COLL LIBERAL ARTS & SCI,DEPT CHEM,OKAYAMA 700,JAPAN
来源：
POLYMER | 1993年 / 34卷 / 07期
关键词：
POLY(CROWN ETHER); ION CONDUCTION; CATION SELECTIVITY; ALKALI METAL ION;
D O I：
10.1016/0032-3861(93)90874-A
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Poly(diaza-18-crown-6) (1) was mixed with alkali metal perchlorates (MClO4; M = Li, Na, K, Rb and Cs). Curved Arrhenius plots for ion conductivity were found for all dry samples, suggesting that ion migration occurs with segmental motion in 1. The potassium cation showed the lowest ion conductivity, reflecting a stronger interaction with the crown ether structure.
引用
收藏
页码：1533 / 1534
页数：2
相关论文
共 50 条
  • [21] BENZOCROWN ETHER HYDRAZONES AS EXTRACTANTS FOR ALKALI-METAL IONS
    SAKAMOTO, H
    GOTO, H
    YOKOSHIMA, M
    DOBASHI, M
    ISHIKAWA, J
    DOI, K
    OTOMO, M
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1993, 66 (10) : 2907 - 2914
  • [22] DIAZA-CROWN ETHER CAPPED CYCLODEXTRIN - A RECEPTOR WITH 2 RECOGNITION SITES
    WILLNER, I
    GOREN, Z
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (24) : 1469 - 1470
  • [23] A novel profluorescent paramagnetic diaza-crown ether: synthesis, characterization and alkaline metal-ion complexation
    Coman, Anca G.
    Stavarache, Cristina
    Paun, Anca
    Popescu, Codruta C.
    Hadade, Niculina D.
    Ionita, Petre
    Matache, Mihaela
    RSC ADVANCES, 2019, 9 (11) : 6078 - 6083
  • [24] CHROMOIONOPHORE AND FLUOROIONOPHORES BASED ON DIAZA-CROWN ETHERS FOR ALKALINE-EARTH METAL-IONS
    BLAIR, TL
    DESAI, J
    BACHAS, LG
    ANALYTICAL LETTERS, 1992, 25 (10) : 1823 - 1834
  • [25] Transition metal complexes of a diaza-crown ether with two carbamoylmethyl substituents: synthesis and assessment as a functional nuclease
    Xie, Jia-qing
    Cai, Shu-lan
    Feng, Fa-mei
    PROGRESS IN REACTION KINETICS AND MECHANISM, 2017, 42 (02) : 136 - 144
  • [26] DNA binding and cleavage properties of the Ce(III) complex of a diaza-crown ether
    Li, Fangzhen
    Feng, Famei
    Wu, Jiaoyi
    Xie, Jiaqing
    Li, Shuo
    PROGRESS IN REACTION KINETICS AND MECHANISM, 2016, 41 (01) : 39 - 47
  • [27] A FLUORESCENCE PROBE INVESTIGATION OF THE EFFECT OF ALKALI-METAL IONS ON THE MICELLAR PROPERTIES OF A CROWN-ETHER SURFACTANT
    TURRO, NJ
    KUO, PL
    JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (05): : 837 - 841
  • [28] BINUCLEAR SILVER (I) COMPLEX WITH DOUBLE ARMED DIAZA-CROWN ETHER CONTAINING SHORT METAL-METAL SEPARATION
    HIROTSU, K
    MIYAHARA, I
    HIGUCHI, T
    TODA, M
    TSUKUBE, H
    MATSUMOTO, K
    CHEMISTRY LETTERS, 1992, (04) : 699 - 702
  • [29] Solvent extraction of alkaline earth metal ions with diaza-crown ethers having two acylpyrazolone moieties
    Umetani, Shigeo
    Ito, Makoto
    Shimojo, Shinichiro
    Kurahashi, Kensuke
    Yamazaki, Shoko
    Ogura, Kaoru
    SOLVENT EXTRACTION RESEARCH AND DEVELOPMENT-JAPAN, 2006, 13 : 185 - 190
  • [30] THE EXTRACTION OF ALKALI-METAL PICRATES BY POLYURETHANE FOAM USING CROWN ETHER
    KHAN, AS
    BALDWIN, WG
    CHOW, A
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1981, 59 (10): : 1490 - 1496
12345