SELECTIVE CONDUCTION OF ALKALI-METAL IONS IN POLY(DIAZA-CROWN ETHER)

被引：7
|
作者：
OHNO, H [1 ]
YAMAZAKI, H [1 ]
TSUKUBE, H [1 ]
机构：
[1] OKAYAMA UNIV,COLL LIBERAL ARTS & SCI,DEPT CHEM,OKAYAMA 700,JAPAN
来源：
POLYMER | 1993年 / 34卷 / 07期
关键词：
POLY(CROWN ETHER); ION CONDUCTION; CATION SELECTIVITY; ALKALI METAL ION;
D O I：
10.1016/0032-3861(93)90874-A
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Poly(diaza-18-crown-6) (1) was mixed with alkali metal perchlorates (MClO4; M = Li, Na, K, Rb and Cs). Curved Arrhenius plots for ion conductivity were found for all dry samples, suggesting that ion migration occurs with segmental motion in 1. The potassium cation showed the lowest ion conductivity, reflecting a stronger interaction with the crown ether structure.
引用
收藏
页码：1533 / 1534
页数：2
相关论文
共 23 条
  • [1] CONDUCTION OF ALKALI-METAL CATIONS IN POLY(DIAZA-CROWN ETHER)S HAVING HYDROXYETHYL SIDE ARMS
    OHNO, H
    INOUE, Y
    TSUKUBE, H
    POLYMER, 1994, 35 (26) : 5753 - 5757
  • [2] Effect of substituted phenolates as a counterion on the ion-pair extraction of alkali metal ions using crown ether
    Nakagawa, H
    Hirayama, N
    Honjo, T
    BUNSEKI KAGAKU, 2003, 52 (09) : 839 - 842
  • [3] Selective exchange of alkali metal ions on EAB zeolite
    Tong, Yansi
    Yuan, Danhua
    Zhang, Wenna
    Wei, Yingxu
    Liu, Zhongmin
    Xu, Yunpeng
    JOURNAL OF ENERGY CHEMISTRY, 2021, 58 : 41 - 47
  • [4] Proton Conduction in Troger's Base-Linked Poly(crown ether)s
    Patel, Hasmukh A.
    Selberg, John
    Salah, Dhafer
    Chen, Haoyuan
    Liao, Yijun
    Nalluri, Siva Krishna Mohan
    Farha, Omar K.
    Snurr, Randall Q.
    Rolandi, Marco
    Stoddart, J. Fraser
    ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (30) : 25303 - 25310
  • [5] Neutralization of keV-energy alkali-metal ions colliding at gold surfaces
    Xiao, Yunqing
    Shi, Yuanqing
    Liu, Pinyang
    Zhu, Yachao
    Gao, Lei
    Guo, Yanling
    Chen, Lin
    Chen, Ximeng
    Esaulov, Vladimir A.
    NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2019, 450 : 73 - 76
  • [6] Electroreduction of aliphatic esters by using alkali metal ion-crown ether complexes as mediators
    Ishifune, M
    Yamashita, H
    Matsuda, M
    Kera, Y
    Yamashita, N
    Kashimura, S
    ELECTROCHIMICA ACTA, 2003, 48 (13) : 1879 - 1884
  • [7] Conformational effect on the preferential binding of alkali metal cation with crown ether: A molecular level investigation
    De, Sulagna
    Ali, Sk Musharaf
    Shenoi, M. R. K.
    Ghosh, Sandip K.
    Maity, Dilip K.
    DESALINATION AND WATER TREATMENT, 2009, 12 (1-3) : 93 - 99
  • [8] Selective complexation of alkali metal ions and nanotubular cyclopeptides: a DFT study
    Chermahini, Alireza Najafi
    Rezapour, Mehdi
    Teimouri, Abbas
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2014, 79 (1-2) : 205 - 214
  • [9] Selective complexation of alkali metal ions and nanotubular cyclopeptides: a DFT study
    Alireza Najafi Chermahini
    Mehdi Rezapour
    Abbas Teimouri
    Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2014, 79 : 205 - 214
  • [10] Crown-Ether Type Podands as Alkali Metal Cation Extractants: Influence of the Number of Oxygens in the Chain
    Valente, Mario
    Sousa, Sergio Filipe
    Magalhaes, Alexandre Lopes
    Freire, Cristina
    JOURNAL OF SOLUTION CHEMISTRY, 2010, 39 (08) : 1230 - 1242
123