INTRAMOLECULAR CYCLIZATION REACTIONS BY USE OF ORGANOLITHIUM COMPOUNDS

被引：0
|
作者：
SAEKI, S
机构：
来源：
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 1992年 / 50卷 / 03期
关键词：
ORGANOLITHIUM COMPOUND; LITHIATION; INTRAMOLECULAR CYCLIZATION REACTION; 5 MEMBERED RING FORMATION; SHAPIRO REACTION; PARHAM REACTION;
D O I：
10.5059/yukigoseikyokaishi.50.213
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Any reaction that results in ring formation can be of considerable potential use in organic synthesis. Nucleophilic center introduced through various kinds of lithiation undergoes intramolecular bond-forming reaction with the internal electrophilic center. Furthermore, the lithiated intermediate generated in this reaction reacts with various electrophiles to afford the products which have the substituents originated from electrophiles. This paper reviews the intramolecular cyclization reaction initiated through organolithium compounds.
引用
收藏
页码：213 / 224
页数：12
相关论文
共 50 条
  • [31] REACTIONS OF BICYCLOPENTADIENYL DERIVATIVES OF ZIRCONIUM WITH ORGANOLITHIUM COMPOUNDS
    RAZUVAEV, GA
    VYSHINSKAIA, LI
    VASILIEVA, GA
    MALYSHEVA, AV
    DOKLADY AKADEMII NAUK SSSR, 1978, 243 (05): : 1212 - 1214
  • [32] REACTIONS OF OXIMES WITH ORGANOLITHIUM COMPOUNDS - SYNTHESIS OF HYDROXYLAMINES
    RICHEY, HG
    MCLANE, RC
    PHILLIPS, CJ
    TETRAHEDRON LETTERS, 1976, (04) : 233 - 234
  • [33] Intramolecular carbolithiation reactions of chiral α-amino-organolithium species
    Ashweek, NJ
    Coldham, I
    Snowden, DJ
    Vennall, GP
    CHEMISTRY-A EUROPEAN JOURNAL, 2002, 8 (01) : 195 - 207
  • [34] ADDITION REACTIONS OF ISOCYANIDES AND ISOCYANOSTYRENES WITH ORGANOLITHIUM COMPOUNDS
    SMETS, G
    ADRIAENS.L
    VANAEL, R
    CALUWE, P
    MAKROMOLEKULARE CHEMIE, 1971, 145 (JUL): : 149 - &
  • [35] Intramolecular cyclization reactions of carbonyl derivatives of hydroxysulfones
    Jin, CY
    Jacobs, HK
    Cervantes-Lee, F
    Gopalan, AS
    TETRAHEDRON, 2002, 58 (19) : 3737 - 3746
  • [36] Prodrug strategies based on intramolecular cyclization reactions
    Shan, DX
    Nicolaou, MG
    Borchardt, RT
    Wang, BH
    JOURNAL OF PHARMACEUTICAL SCIENCES, 1997, 86 (07) : 765 - 767
  • [37] INTRAMOLECULAR CYCLIZATION IN REACTIONS OF BICYCLIC DIEPOXIDES WITH DIMETHYLAMINES
    KASYAN, LI
    ZEFIROV, NS
    STEPANOVA, NV
    SALTYKOVA, LE
    RYZHIK, OL
    ZHURNAL ORGANICHESKOI KHIMII, 1984, 20 (10): : 2136 - 2143
  • [38] SYNTHESIS AND REACTIONS OF ORGANOLITHIUM AND -MAGNESIUM COMPOUNDS OF PERFLUORODIPHENYL ETHERS
    DEPASQUALE, RJ
    TAMBORSKI, C
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1968, 13 (02) : 273 - +
  • [39] Alkylation of cyclopentadienyl rings in the reactions of nickelocene with organolithium compounds
    Pasynkiewicz, S
    Pietrzykowski, A
    Bukowska, L
    Jerzykiewicz, L
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 585 (02) : 308 - 314
  • [40] Intramolecular cyclization reactions of arylpropargyl amides of electron-deficient α,β-alkenyl carboxylates and related compounds
    Wang, Zhichao
    Yamazaki, Shoko
    Morimoto, Tsumoru
    Takashima, Hiroshi
    Nakaoku, Ayane
    Shimizu, Makoto
    Ogawa, Akiya
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2023, 21 (10) : 2172 - 2187
12345